Asymmetric hydrogenation of 1-phenylethenylboronic acid and esters for the synthesis of chiral organoboron compounds
作者： Masato Ueda , Atsushi Saitoh , Norio Miyaura
DOI: 10.1016/S0022-328X(01)01239-6
关键词: Organoboron compounds 、 Asymmetric hydrogenation 、 Chemistry 、 Noyori asymmetric hydrogenation 、 Enantioselective synthesis 、 Hydrogen atmosphere 、 Hydrogen peroxide 、 Organic chemistry
摘要: Abstract The hydrogenation of ethanediol 1-phenylethenylboronic ester was carried out at −20 °C under a hydrogen atmosphere (9 atm) in the presence [Rh(cod)2]BF4–(R)-BINAP (3 mol%). After alkaline peroxide oxidation, reaction gave 1-phenylethanol with 80% e.e.
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