Speciation of Trace Di- and Triorganotins in Water by Ion-Exchange HPLC-GFAA

作者: K. L. Jewett , F. E. Brinckman

DOI: 10.1093/CHROMSCI/19.11.583

关键词: Inorganic chemistryChromatographyChemistryTinAnalytical chemistryColumn chromatographyBiocideDetection limitIon-exchange resinLeaching (metallurgy)High-performance liquid chromatographyGraphite

摘要: Abstract : Based on their behavior as stable cations in saline solutions, direct trace speciation of a broad range organotins, representing current industrial or environmental interests, was performed by combination an tin-specific graphite furnace atomic detector with HPLC employing reverse bonded-phase strong exchange columns. Column and system performance detection limits (5-30 ng tin) vary predictably individual substituents but are easily optimized, for example, identifying marine antifoulant leachates. (Author)

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