Thiocarbonyl quinacridone-based "turn on" fluorescent chemodosimeters for highly sensitive and selective detection of Hg(II)

作者: Yi Qu , Jiabao Yang , Jianli Hua , Lei Zou

DOI: 10.1016/J.SNB.2011.10.087

关键词: Metal ions in aqueous solutionHighly sensitiveFluorescenceDetection limitMercury (element)ChloroformChemistryPhotochemistryQuinacridoneIon

摘要: Abstract Two new thiocarbonyl quinacridone compounds (TQA-H and TQA-TPA) were designed synthesized, their fluorescent behaviors toward various metal ions investigated. The measurements of sensing behavior to reveal that both them are excellent “turn on” chemosensors for mercury ion. Addition Hg2+ the chloroform solution TQA-TPA gave lowest detection limit at 4.7 nM. In addition, colorimetric changes sensors interacted with also successfully demonstrated. recognition is attributed Hg2+-induced conversion quinacridones into carbonyl analogues.

参考文章(28)
Mi Young Chae, Anthony W. Czarnik, Fluorimetric chemodosimetry. Mercury(II) and silver(I) indication in water via enhanced fluorescence signaling Journal of the American Chemical Society. ,vol. 114, pp. 9704- 9705 ,(1992) , 10.1021/JA00050A085
Qi Zou, He Tian, Chemodosimeters for mercury(II) and methylmercury(I) based on 2,1,3-benzothiadiazole Sensors and Actuators B-chemical. ,vol. 149, pp. 20- 27 ,(2010) , 10.1016/J.SNB.2010.06.040
Gilad Mor-Piperberg, Ran Tel-Vered, Johann Elbaz, Itamar Willner, Nanoengineered electrically contacted enzymes on DNA scaffolds: functional assemblies for the selective analysis of Hg2+ ions. Journal of the American Chemical Society. ,vol. 132, pp. 6878- 6879 ,(2010) , 10.1021/JA1006355
Toan V. Pho, Peter Zalar, Andres Garcia, Thuc-Quyen Nguyen, Fred Wudl, Electron injection barrier reduction for organic light-emitting devices by quinacridone derivatives Chemical Communications. ,vol. 46, pp. 8210- 8212 ,(2010) , 10.1039/C0CC01596B
Min Hee Lee, Byoung-Ki Cho, Juyoung Yoon, Jong Seung Kim, Selectively Chemodosimetric Detection of Hg(II) in Aqueous Media Organic Letters. ,vol. 9, pp. 4515- 4518 ,(2007) , 10.1021/OL7020115
Jiangli Fan, Kexin Guo, Xiaojun Peng, Jianjun Du, Jingyun Wang, Shiguo Sun, Honglin Li, A Hg2+ fluorescent chemosensor without interference from anions and Hg2+-imaging in living cells Sensors and Actuators B: Chemical. ,vol. 142, pp. 191- 196 ,(2009) , 10.1016/J.SNB.2009.08.002
Elizabeth M. Nolan, Stephen J. Lippard, Tools and tactics for the optical detection of mercuric ion. Chemical Reviews. ,vol. 108, pp. 3443- 3480 ,(2008) , 10.1021/CR068000Q
Shaoming Duan, Jeff Turk, Joseph Speigle, Jean Corbin, John Masnovi, Ronald J. Baker, Halogenations of Anthracenes and Dibenz[a,c]anthracene with N-Bromosuccinimide and N-Chlorosuccinimide1 Journal of Organic Chemistry. ,vol. 65, pp. 3005- 3009 ,(2000) , 10.1021/JO991495H
Qi Zou, Jiayu Jin, Bo Xu, Li Ding, He Tian, New photochromic chemosensors for Hg2+ and F- Tetrahedron. ,vol. 67, pp. 915- 921 ,(2011) , 10.1016/J.TET.2010.12.019
Chuandong Dou, Di Li, Hongze Gao, Chunyu Wang, Hongyu Zhang, Yue Wang, Sonication-Induced Molecular Gels Based on Mono-Cholesterol Substituted Quinacridone Derivatives Langmuir. ,vol. 26, pp. 2113- 2118 ,(2010) , 10.1021/LA902663Z