Improvement of holographic performance by novel photopolymer systems with siloxane-containing epoxides

作者: Yeong Hee Cho , Man He , Byung Kyu Kim , Yusuke Kawakami

DOI: 10.1016/J.STAM.2003.12.016

关键词: PhotochemistryMaterials scienceSiloxaneCyclohexanePhotopolymerOxideCuring (chemistry)Liquid crystalDiffraction efficiencyAcrylate

摘要: Diffraction efficiency and morphology of holographic gratings were improved by combining ring-opening polymerizable epoxides with radical conventional acrylate systems. By adding epoxide materials, the grating spacings increased when compared case where only was used. The effects especially notable for cyclohexane oxide derivatives. diffraction highest, nanoscale phase-separated liquid crystal domains most clearly formed using siloxane-containing group, due to their incompatibility fast curing.

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