Catalytic activity of Co/MCM-41 and Co/SBA-15 materials in toluene oxidation
作者： Ágnes Szegedi , Margarita Popova , Christo Minchev
DOI: 10.1007/S10853-009-3600-Y
关键词: Toluene oxidation 、 Mesoporous material 、 Catalysis 、 Cobalt oxide 、 MCM-41 、 Inorganic chemistry 、 Physisorption 、 Mesoporous organosilica 、 Materials science 、 Cobalt 、 Chemical engineering
摘要: Cobalt-containing MCM-41 and SBA-15 mesoporous materials were prepared by the pH-adjusting of impregnation solution. The modified investigated X-ray diffraction, N2 physisorption, temperature-programmed reduction, DR UV–Vis diffuse reflectance, FT-IR spectroscopy adsorbed pyridine. pH solution influences surface charge support therefore determines strength interaction between cobalt precursor support. formation different oxide species in ratios, depending on solution, was established for both materials. Co/MCM-41 Co/SBA-15 active toluene oxidation. Their catalytic activity is predetermined nature, reducibility, dispersion obtained species.
springer.com
harvard.edu
sci-hub.se 参考文章(42)
A Jasik, R Wojcieszak, S Monteverdi, M Ziolek, MM Bettahar, None, Study of nickel catalysts supported on Al2O3, SiO2 or Nb2O5 oxides Journal of Molecular Catalysis A-chemical. ,vol. 242, pp. 81- 90 ,(2005) , 10.1016/J.MOLCATA.2005.07.013
R.S. Araújo, D.C.S. Azevedo, E. Rodríguez-Castellón, A. Jiménez-López, C.L. Cavalcante, Al and Ti-containing mesoporous molecular sieves: Synthesis, characterization and redox activity in the anthracene oxidation Journal of Molecular Catalysis A-chemical. ,vol. 281, pp. 154- 163 ,(2008) , 10.1016/J.MOLCATA.2007.09.001
Enrique Iglesia, Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts Applied Catalysis A: General. ,vol. 161, pp. 59- 78 ,(1997) , 10.1016/S0926-860X(97)00186-5
Joongjai Panpranot, James G Goodwin Jr, Abdelhamid Sayari, Synthesis and characteristics of MCM-41 supported CoRu catalysts Catalysis Today. ,vol. 77, pp. 269- 284 ,(2002) , 10.1016/S0920-5861(02)00252-3
David G. Castner, Philip R. Watson, Ignatius Y. Chan, X-ray absorption spectroscopy, x-ray photoelectron spectroscopy, and analytical electron microscopy studies of cobalt catalysts. 2. Hydrogen reduction properties The Journal of Physical Chemistry. ,vol. 94, pp. 819- 828 ,(1990) , 10.1021/J100365A057
Eric van Steen, Gary S. Sewell, Rafene A. Makhothe, Craig Micklethwaite, Heiko Manstein, Martijn de Lange, Cyril T. O'Connor, TPR Study on the Preparation of Impregnated Co/SiO2Catalysts Journal of Catalysis. ,vol. 162, pp. 220- 229 ,(1996) , 10.1006/JCAT.1996.0279
Zhensong Lou, Ruiheng Wang, Hui Sun, Yuan Chen, Yanhui Yang, Direct synthesis of highly ordered Co-SBA-15 mesoporous materials by the pH-adjusting approach Microporous and Mesoporous Materials. ,vol. 110, pp. 347- 354 ,(2008) , 10.1016/J.MICROMESO.2007.06.020
H MING, B BAKER, Characterization of cobalt Fischer-Tropsch catalysts I. Unpromoted cobalt-silica gel catalysts Applied Catalysis A-general. ,vol. 123, pp. 23- 36 ,(1995) , 10.1016/0926-860X(94)00220-7
D. Zhao, Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Science. ,vol. 279, pp. 548- 552 ,(1998) , 10.1126/SCIENCE.279.5350.548
Kyriakos Bourikas, Christos Kordulis, John Vakros, Alexis Lycourghiotis, Adsorption of cobalt species on the interface, which is developed between aqueous solution and metal oxides used for the preparation of supported catalysts: a critical review Advances in Colloid and Interface Science. ,vol. 110, pp. 97- 120 ,(2004) , 10.1016/J.CIS.2004.04.001