Chirality Control in Oligothiophene through Chiral Wrapping
作者： Takanobu Sanji , Nobu Kato , Masato Tanaka
DOI: 10.1021/OL052494G
关键词: Chemistry 、 Chirality (chemistry) 、 Carbohydrate conformation 、 Polymer 、 Polymer chemistry 、 Schizophyllan 、 Molecule
摘要: [structure: see text] Mixing oligothiophenes and polysaccharides, such as amylose schizophyllan, affords novel inclusion complexes, in which oligothiophene guests adopt twisted conformation the chiral channel created by left- or right-handed helical wrapping with polysaccharide host polymers, leading to optical activity.
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