Pyrolytically grown arrays of highly aligned BxCyNz nanotubes
作者： Wei-Qiang Han , John Cumings , Alex Zettl
DOI: 10.1063/1.1369620
关键词: Electron energy loss spectroscopy 、 Transmission electron microscopy 、 Carbon nanotube 、 Scanning electron microscope 、 Stoichiometry 、 Nanotube 、 Spectroscopy 、 Analytical chemistry 、 Crystal structure
摘要: A pyrolysis route has been used to synthesize arrays of highly aligned BxCyNz nanotubes in bulk. The structure and composition the product were characterized by scanning electron microscopy, high-resolution transmission energy-loss spectroscopy. length diameter are quite uniform a large area reaction zone. sizes from whole zone 10–30 μm 20–140 nm diameter. x/z ratio for most is about 1:1. x/y up 0.6. Within one nanotube, usually heterogeneous. growth mechanism also discussed.
scitation.org
harvard.edu
osti.gov
aip.org
sci-hub.se 参考文章(20)
Wei-Qiang Han, Philipp Kohler-Redlich, Torsten Seeger, Frank Ernst, Manfred Rühle, Nicole Grobert, Wen-Kuang Hsu, Bao-He Chang, Yan-Qiu Zhu, Harold W. Kroto, David R. M. Walton, Mauricio Terrones, Humberto Terrones, Aligned CNx nanotubes by pyrolysis of ferrocene/C60 under NH3 atmosphere Applied Physics Letters. ,vol. 77, pp. 1807- 1809 ,(2000) , 10.1063/1.1311813
M. Terrones, N. Grobert, J. Olivares, J. P. Zhang, H. Terrones, K. Kordatos, W. K. Hsu, J. P. Hare, P. D. Townsend, K. Prassides, A. K. Cheetham, H. W. Kroto, D. R. M. Walton, Controlled production of aligned-nanotube bundles Nature. ,vol. 388, pp. 52- 55 ,(1997) , 10.1038/40369
Weiqiang Han, Yoshio Bando, Keiji Kurashima, Tadao Sato, Synthesis of boron nitride nanotubes from carbon nanotubes by a substitution reaction Applied Physics Letters. ,vol. 73, pp. 3085- 3087 ,(1998) , 10.1063/1.122680
W. Han, Synthesis of Gallium Nitride Nanorods Through a Carbon Nanotube-Confined Reaction Science. ,vol. 277, pp. 1287- 1289 ,(1997) , 10.1126/SCIENCE.277.5330.1287
Y. Zhang, H. Gu, K. Suenaga, S. Iijima, Heterogeneous growth of BCN nanotubes by laser ablation Chemical Physics Letters. ,vol. 279, pp. 264- 269 ,(1997) , 10.1016/S0009-2614(97)01048-8
K Suenaga, C Colliex, N Demoncy, A Loiseau, H Pascard, F Willaime, Synthesis of Nanoparticles and Nanotubes with Well-Separated Layers of Boron Nitride and Carbon Science. ,vol. 278, pp. 653- 655 ,(1997) , 10.1126/SCIENCE.278.5338.653
Yoshiyuki Miyamoto, Marvin L. Cohen, Steven G. Louie, Theoretical investigation of graphitic carbon nitride and possible tubule forms Solid State Communications. ,vol. 102, pp. 605- 608 ,(1997) , 10.1016/S0038-1098(97)00025-2
Sumio Iijima, Helical microtubules of graphitic carbon Nature. ,vol. 354, pp. 56- 58 ,(1991) , 10.1038/354056A0
Masako Yudasaka, Rie Kikuchi, Takeo Matsui, Yoshimasa Ohki, Susumu Yoshimura, Etsuro Ota, Specific conditions for Ni catalyzed carbon nanotube growth by chemical vapor deposition Applied Physics Letters. ,vol. 67, pp. 2477- 2479 ,(1995) , 10.1063/1.114613
Ph. Redlich, J. Loeffler, P.M. Ajayan, J. Bill, F. Aldinger, M. Rühle, BCN nanotubes and boron doping of carbon nanotubes Chemical Physics Letters. ,vol. 260, pp. 465- 470 ,(1996) , 10.1016/0009-2614(96)00817-2