Measured capillary forces on spheres at particle-laden interfaces

作者: Wei He , Nesrin Şenbil , A. D. Dinsmore

DOI: 10.1039/C5SM00245A

关键词: Capillary actionSPHERESCantileverPerpendicularMechanicsDeflection (physics)Particle sizeMaterials scienceClassical mechanicsElectrodipping forcePull force

摘要: We measure capillary forces on particles at fluid interfaces in order to assess the key parameters that yield effective stabilizing particles. In our experiments, a millimeter-scale particle is attached cantilever, which used pull perpendicular interface. Simultaneously, we image from side cantilever's deflection and thus pulling force, as well height of shape find peak force an interface crowded with other consistently smaller than clean This result independent difference mass densities, material target sphere, charge free attribute reduction perturbation due constraints boundaries The results should be helpful designing stabilize droplets new oil dispersants or applications.

参考文章(29)
G D Yarnold, The hysteresis of the angle of contact of mercury Proceedings of the Physical Society. ,vol. 58, pp. 120- 125 ,(1946) , 10.1088/0959-5309/58/1/312
Y Lin, H Skaff, Todd Emrick, AD Dinsmore, Thomas P Russell, Nanoparticle Assembly and Transport at Liquid-Liquid Interfaces Science. ,vol. 299, pp. 226- 229 ,(2003) , 10.1126/SCIENCE.1078616
Joseph W. Krumpfer, Thomas J. McCarthy, Contact angle hysteresis: a different view and a trivial recipe for low hysteresis hydrophobic surfaces Faraday Discussions. ,vol. 146, pp. 103- 111 ,(2010) , 10.1039/B925045J
A. D. Scheludko, D. Nikolov, Measurement of surface tension by pulling a sphere from a liquid Colloid and Polymer Science. ,vol. 253, pp. 396- 403 ,(1975) , 10.1007/BF01382159
Graeme Gillies, Michael Kappl, Hans-Jürgen Butt, Direct measurements of particle-bubble interactions. Advances in Colloid and Interface Science. ,vol. 114, pp. 165- 172 ,(2005) , 10.1016/J.CIS.2004.08.003
A. Domínguez, D. Frydel, M. Oettel, Multipole expansion of the electrostatic interaction between charged colloids at interfaces. Physical Review E. ,vol. 77, pp. 020401- ,(2008) , 10.1103/PHYSREVE.77.020401
Robert Aveyard, Bernard P Binks, John H Clint, Emulsions stabilised solely by colloidal particles Advances in Colloid and Interface Science. ,vol. 100, pp. 503- 546 ,(2003) , 10.1016/S0001-8686(02)00069-6
Pawel Pieranski, Two-Dimensional Interfacial Colloidal Crystals Physical Review Letters. ,vol. 45, pp. 569- 572 ,(1980) , 10.1103/PHYSREVLETT.45.569