Bioethanol Production From Hydrolyzed Lignocellulosic After Detoxification Via Adsorption With Activated Carbon and Dried Air Stripping.

作者: Wagner Artifon , Charline Bonatto , Eduarda R. Bordin , Suzana F. Bazoti , Adriana Dervanoski

DOI: 10.3389/FBIOE.2018.00107

关键词: LangmuirAir strippingLangmuir adsorption modelFreundlich equationActivated carbonAdsorptionChemical engineeringAcetic acidChemistryHydrolysis

摘要: Bioethanol production has been presented as an alternative for supplying energy demand and minimizing greenhouse gases effects. However, due to abrasively conditions employed on the biomass during pretreatment hydrolysis processes, inhibitors fermentation phase such acetic acid others can be generated. Based this problem, aim of work was evaluate adsorption microporous activated carbon investigate stripping same component with dried air. For process, three concentrations (5, 10, 20%) were analyzed by kinetics isotherms (Langmuir Freundlich models). Pseudo-second order model showed fit better when compared Pseudo-first model. The Intraparticle Diffusion first regulating step process. Langmuir best fitting, maximum capacity found 128.66 mg.g-1. procedure apparatus set in insert air a diffusor within solution study. Increasing temperature determinant augmenting evaporation 2.14 6.22 times 40 60°C comparing it 20°C. application pickling process removal sugarcane bagasse hydrolyzed allowed 8.3 g.L-1 ethanol.

参考文章(25)
W. Fritz, W. Merk, E.U. Schlünder, Competitative adsorption of two dissolved organics onto activated carbon—II: Adsorption kinetics in batch reactors Chemical Engineering Science. ,vol. 36, pp. 743- 757 ,(1981) , 10.1016/0009-2509(81)85089-0
Yaqin Zhang, Ming Li, Yafei Wang, Xiaosheng Ji, Lin Zhang, Lian Hou, Simultaneous concentration and detoxification of lignocellulosic hydrolyzates by vacuum membrane distillation coupled with adsorption. Bioresource Technology. ,vol. 197, pp. 276- 283 ,(2015) , 10.1016/J.BIORTECH.2015.08.097
Thawatchai Maneerung, Johan Liew, Yanjun Dai, Sibudjing Kawi, Clive Chong, Chi-Hwa Wang, Activated carbon derived from carbon residue from biomass gasification and its application for dye adsorption: Kinetics, isotherms and thermodynamic studies Bioresource Technology. ,vol. 200, pp. 350- 359 ,(2016) , 10.1016/J.BIORTECH.2015.10.047
Hongzhi Huang, Xinyan Guo, Dongmin Li, Mengmeng Liu, Jiafang Wu, Haiyu Ren, Identification of crucial yeast inhibitors in bio-ethanol and improvement of fermentation at high pH and high total solids Bioresource Technology. ,vol. 102, pp. 7486- 7493 ,(2011) , 10.1016/J.BIORTECH.2011.05.008
Yuh-Shan Ho, Gordon McKay, SORPTION OF DYE FROM AQUEOUS SOLUTION BY PEAT Chemical Engineering Journal. ,vol. 70, pp. 115- 124 ,(1998) , 10.1016/S0923-0467(98)00076-1
Beatriz Gutiérrez-Rivera, Beningo Ortiz-Muñiz, Javier Gómez-Rodríguez, Angel Cárdenas-Cágal, José Manuel Domínguez González, Maria Guadalupe Aguilar-Uscanga, Bioethanol production from hydrolyzed sugarcane bagasse supplemented with molasses "B" in a mixed yeast culture. Renewable Energy. ,vol. 74, pp. 399- 405 ,(2015) , 10.1016/J.RENENE.2014.08.030
S. Mohan, R. Gandhimathi, Removal of heavy metal ions from municipal solid waste leachate using coal fly ash as an adsorbent Journal of Hazardous Materials. ,vol. 169, pp. 351- 359 ,(2009) , 10.1016/J.JHAZMAT.2009.03.104
Lotfi Sellaoui, Hanen Guedidi, Salah Knani, Laurence Reinert, Laurent Duclaux, Abdelmottaleb Ben Lamine, Application of statistical physics formalism to the modeling of adsorption isotherms of ibuprofen on activated carbon Fluid Phase Equilibria. ,vol. 387, pp. 103- 110 ,(2015) , 10.1016/J.FLUID.2014.12.018