The i.r. spectrum of solid hypofluorous acid, HOF
作者： Evan H. Appelman , William W. Wilson , Hyunyong Kim
DOI: 10.1016/0584-8539(81)80108-0
关键词: Normal mode 、 Hypofluorous acid 、 Planar 、 Analytical chemistry 、 Computational chemistry 、 Dimer 、 Internal mode 、 Chemistry 、 Intermolecular force 、 Crystallographic data 、 Spectral line
摘要: Abstract The i.r. spectra of solid films hypofluorous acid, HOF, have been measured at −195°C between 300 and 4000 cm −1 . the isotopic species DOF H 18 OF also measured. Bands corresponding to internal vibration modes are observed 3370, 3285, 1397 885 for HOF; 2490, 2445, 1037 887 DOF; 1390 858 OF. In addition, intermolecular bands 628 448 575, 467 340 HOF/DOF mixtures; 630 449 samples deposited liquid N 2 temperature initially show rather broad mode no discernible bands, but upon standing or slight warming sharpen appear. interpreted in terms a simple cyclic dimer. However, alternative structures involving infinite planar zig-zag chains cannot be ruled out absence crystallographic data.
harvard.edu
elsevier.com
sci-hub.se 参考文章(15)
Evan H. Appelman, Hyunyong Kim, Gas‐Phase Infrared Spectra of HOF and DOF The Journal of Chemical Physics. ,vol. 57, pp. 3272- 3276 ,(1972) , 10.1063/1.1678752
William D. Gwinn, Normal Coordinates: General Theory, Redundant Coordinates, and General Analysis Using Electronic Computers The Journal of Chemical Physics. ,vol. 55, pp. 477- 481 ,(1971) , 10.1063/1.1675776
J. Berkowitz, E. H. Appelman, W. A. Chupka, Photoionization of HOF with mass analysis The Journal of Chemical Physics. ,vol. 58, pp. 1950- 1954 ,(1973) , 10.1063/1.1679456
J. C. Hindman, A. Svirmickas, E. H. Appelman, Proton and Fluorine Nuclear Magnetic Resonance Observations on Hypofluorous Acid, HOF Journal of Chemical Physics. ,vol. 57, pp. 4542- 4543 ,(1972) , 10.1063/1.1678113
Edwin F. Pearson, Hyunyong Kim, Centrifugal Distortion Analysis of Hypofluorous Acid: HOF and DOF The Journal of Chemical Physics. ,vol. 57, pp. 4230- 4233 ,(1972) , 10.1063/1.1678053
Hyunyong Kim, Edwin F. Pearson, Evan H. Appelman, Millimeter‐Wave Spectrum and Structure of Hypofluorous Acid: HOF and DOF The Journal of Chemical Physics. ,vol. 56, pp. 1- 3 ,(1972) , 10.1063/1.1676830
S. L. Rock, E. F. Pearson, E. H. Appleman, C. L. Norris, W. H. Flygare, Molecular rotational Zeeman effect in HOF, a comparison with H2O, F2O, and other fluorine containing molecules; and dipole moments of HOF and DOF The Journal of Chemical Physics. ,vol. 59, pp. 3940- 3945 ,(1973) , 10.1063/1.1680582
J. Berkowitz, J.L. Dehmer, E.H. Appelman, Photoelectron spectrum of hypofluorous acid, HOF Chemical Physics Letters. ,vol. 19, pp. 334- 336 ,(1973) , 10.1016/0009-2614(73)80372-0
J. S. Kittelberger, D. F. Hornig, Vibrational Spectrum of Crystalline HF and DF The Journal of Chemical Physics. ,vol. 46, pp. 3099- 3108 ,(1967) , 10.1063/1.1841181
John Tyson, Howard H. Claassen, Hyunyong Kim, Molecular Potential Functions Expressed in Cartesian Coordinates: Application to the Orbital Valency Force Field The Journal of Chemical Physics. ,vol. 54, pp. 3142- 3156 ,(1971) , 10.1063/1.1675302