Synthesis of dendritic polyolefins by metathesis insertion polymerization
作者： Andy Haishung Tsou , Yong Yang
DOI:
关键词: Ring-opening metathesis polymerisation 、 Catalysis 、 Polymer 、 Hydrocarbon 、 Polymerization 、 Materials science 、 Polymer chemistry 、 One-Step 、 Metathesis 、 Polyolefin
摘要: A one step process for making a dendritic hydrocarbon polymer, e.g., polyolefin, by metathesis insertion polymerization. The comprises polymerizing an amount of or more cyclic olefins and multi-functional (meth)acrylates in the presence catalyst under conditions sufficient to produce polymer. have functionality 3 higher. polymer can be hydrogenated substantially saturated hydrogenation take place same reaction vessel as polymerization, i.e., pot process.
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