Molecular complexes of paraquat with anilines

作者: P Padma , T Vinod Kumar , T Charan Singh , G Venkateshwarlu , None

DOI: 10.1007/BF02841440

关键词: Spectral lineAbsorption (chemistry)MethanolWavelengthPhotochemistryChemistryIonizationRing (chemistry)ParaquatAqueous solution

摘要: The U V-VIS spectra of molecular complexes paraquat with ring and N-substituted anilines have been recorded in methanol 50% v/v aqueous methanol. All the exhibited well-resolved charge transfer bands wavelength region where neither components any absorption. energies substituted aniline-paraquat bear linear relationships ionization potentials obtained from aniline-TCNE complexes, indicating π - interaction between donors. Both N-substituents effects on positions CT as well stabilities complexes. are shifted to shorter wavelengths decrease going aqueous.

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