The Covalent Functionalization of Graphene on Substrates.

摘要: The utilization of grown or deposited graphene on solid substrates offers key benefits for functionalization processes, but especially to attain structures with a high level control electronics and "smart" materials. In this review, we will initially focus the nature properties substrates, based method preparation. We then analyze most relevant literature substrates. particular, comparatively discuss radical reactions, cycloadditions, halogenations, hydrogenations, oxidations. address question how reactivity is affected by its morphology (i.e., number layers, defects, substrate, curvature, etc.).