Mössbauer Spectroscopic Studies of Ferrocenylaldimines and their TCNQ Complexes
作者： Chin-Jhan Lee , Ho-Hsiang Wei
关键词: Condensation 、 Mössbauer effect 、 Schiff base 、 Mössbauer spectroscopy 、 Ferrocene derivatives 、 Inorganic chemistry 、 Crystallography 、 Chemistry
摘要: A series of ferrocenylaldimines (Fc-CH=N-R) has been prepared by Schiff base condensation formylferrocene with polyacenylamines RNH2 where R = naphthyl, 5,6,7,8-tetrahydronaphthyl, anthracenyl, and pyrenyl groups. This step was followed oxidation TCNQ to give [Fc-CH N-R][TCNQ]2 salts. The electronic state iron in these compounds investigated means of57Fe Mossbauer spectroscopy.
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