Sodium phosphate synthesis through glycerol purification and its utilization for biodiesel production from dairy scum oil to economize production cost

作者: K. V. Yatish , H. S. Lalithamba , R. Suresh , G. N. Dayananda

DOI: 10.1039/C8SE00034D

关键词: BiodieselYield (chemistry)CatalysisChemistryBase (chemistry)GlycerolPulp and paper industryPhosphateBiodiesel productionSodium

摘要: In the present study, sodium phosphate was synthesized through glycerol purification. The as-synthesized characterized and effectively utilized as a heterogeneous base catalyst for biodiesel production from dairy waste scum oil. addition, crude same can be used production, which is economically beneficial. Further, maximum oil methyl ester (DSOME/biodiesel) yield of 97.7% achieved under optimum conditions 11 : 1 molar ratio, 4 wt% loading, 65 °C temperature 60 min reaction time with stirring at 700 rpm. activation energy (Ea) transesterification found to 35.56 kJ mol−1.

参考文章(28)
Yie Hua Tan, Mohammad Omar Abdullah, Cirilo Nolasco-Hipolito, Nur Syuhada Ahmad Zauzi, Application of RSM and Taguchi methods for optimizing the transesterification of waste cooking oil catalyzed by solid ostrich and chicken-eggshell derived CaO Renewable Energy. ,vol. 114, pp. 437- 447 ,(2017) , 10.1016/J.RENENE.2017.07.024
K.V. Yatish, H.S. Lalithamba, R. Suresh, H.R. Harsha Hebbar, Optimization of bauhinia variegata biodiesel production and its performance, combustion and emission study on diesel engine Renewable Energy. ,vol. 122, pp. 561- 575 ,(2018) , 10.1016/J.RENENE.2018.01.124
Masoud Zabeti, Wan Mohd Ashri Wan Daud, Mohamed Kheireddine Aroua, Optimization of the activity of CaO/Al2O3 catalyst for biodiesel production using response surface methodology Applied Catalysis A: General. ,vol. 366, pp. 154- 159 ,(2009) , 10.1016/J.APCATA.2009.06.047
Guoqing Guan, Katsuki Kusakabe, Satoko Yamasaki, Tri-potassium phosphate as a solid catalyst for biodiesel production from waste cooking oil Fuel Processing Technology. ,vol. 90, pp. 520- 524 ,(2009) , 10.1016/J.FUPROC.2009.01.008
Zhanyou Chi, Denver Pyle, Zhiyou Wen, Craig Frear, Shulin Chen, A laboratory study of producing docosahexaenoic acid from biodiesel-waste glycerol by microalgal fermentation Process Biochemistry. ,vol. 42, pp. 1537- 1545 ,(2007) , 10.1016/J.PROCBIO.2007.08.008
Martin Hájek, František Skopal, Treatment of glycerol phase formed by biodiesel production. Bioresource Technology. ,vol. 101, pp. 3242- 3245 ,(2010) , 10.1016/J.BIORTECH.2009.12.094
J. C. Thompson, B. B. He, Characterization of crude glycerol from biodiesel production from multiple feedstocks. Applied Engineering in Agriculture. ,vol. 22, pp. 261- 265 ,(2006) , 10.13031/2013.20272
P. Sivakumar, K. Anbarasu, S. Renganathan, Bio-diesel production by alkali catalyzed transesterification of dairy waste scum Fuel. ,vol. 90, pp. 147- 151 ,(2011) , 10.1016/J.FUEL.2010.08.024