Effect of graphene oxide nanoplatelets on electrochemical properties of steel substrate in saline media

作者: A.U. Chaudhry , Vikas Mittal , Brajendra Mishra

DOI: 10.1016/J.MATCHEMPHYS.2015.07.023

关键词: Dielectric spectroscopyCorrosionScanning electron microscopeMaterials scienceChemical engineeringPourbaix diagramGrapheneMetallurgyWorking electrodePrecipitation (chemistry)Oxide

摘要: Abstract There has been increased interest in using graphene oxide (GO) various industrial applications such as working fluids, lubricants, oil and gas fields, heavy metal removal from water, anticorrosion paints coatings etc. We studied electrochemical properties of steel the presence suspended GO saline media. suspension characterized Transmission electron microscopy (TEM) X-ray diffractometer (XRD). measured effect concentration (0–15 ppm) on different techniques: open circuit potential (OCP), impedance spectroscopy (EIS), linear polarization resistance (LPR) potentiodynamic (PD) methods. Results indicate that suppression corrosion is directly proportional to increasing concentrations environments. Surface morphology corroded samples was examined Scanning Electron Microscopy (SEM). Identification elements at accumulated layer estimated peaks energy dispersive x-ray (EDX) XRD. Increased protection abilities with have attributed domination salt surface which occurs via precipitation sodium chloride. analysis confirm there no direct behavior steel. The solution can enhance NaCl due decreased solubility further slows down corrosion. pourbaix diagram shows forms an anionic compound may electrode.

参考文章(38)
Wen Sun, Lida Wang, Tingting Wu, Yanqiu Pan, Guichang Liu, Inhibited corrosion-promotion activity of graphene encapsulated in nanosized silicon oxide Journal of Materials Chemistry. ,vol. 3, pp. 16843- 16848 ,(2015) , 10.1039/C5TA04236D
R.B.A. Nor Asma, P.A. Yuli, C.I. Mokhtar, Study on the Effect of Surface Finish on Corrosion of Carbon Steel in CO2 Environment Journal of Applied Sciences. ,vol. 11, pp. 2053- 2057 ,(2011) , 10.3923/JAS.2011.2053.2057
Ki Youl Yoon, Sung Jin An, Yunshen Chen, Jae Ho Lee, Steven L. Bryant, Rodney S. Ruoff, Chun Huh, Keith P. Johnston, Graphene oxide nanoplatelet dispersions in concentrated NaCl and stabilization of oil/water emulsions. joint international conference on information sciences. ,vol. 403, pp. 1- 6 ,(2013) , 10.1016/J.JCIS.2013.03.012
Xiangzhu Zhou, Jingcheng Hao, Solubility of NaBr, NaCl, and KBr in Surfactant Aqueous Solutions Journal of Chemical & Engineering Data. ,vol. 56, pp. 951- 955 ,(2011) , 10.1021/JE100905G
Jaemyung Kim, Laura J. Cote, Franklin Kim, Wa Yuan, Kenneth R. Shull, Jiaxing Huang, Graphene Oxide Sheets at Interfaces Journal of the American Chemical Society. ,vol. 132, pp. 8180- 8186 ,(2010) , 10.1021/JA102777P