作者: Eero Byckling
DOI: 10.1016/0031-8914(62)90131-3
关键词: Statistical mechanics 、 Connection (mathematics) 、 Mathematics 、 Classical mechanics 、 Molecule 、 Distribution function 、 Helmholtz free energy 、 Integral equation
摘要: Abstract The thermodynamic properties of a rectilinear assembly are solved taking into account the interaction each molecule with any given number n near-by molecules. result is non-linear integral equation, which determines distribution function. connection between this function and Helmholtz free energy derived. method can apparently be extended to higher dimensional cases.