Sorption-desorption behavior of bispyrazolato-copper(II) 1D coordination polymers.

作者： Augusto Cingolani , Simona Galli , Norberto Masciocchi , Luciano Pandolfo , Claudio Pettinari

关键词: X-ray crystallography 、 Inorganic chemistry 、 Crystallite 、 Polymer 、 Crystal structure 、 Chemistry 、 Anhydrous 、 Stereochemistry 、 Molecule 、 Copper 、 Powder diffraction

摘要: A new polycrystalline vapochromic polymorph of the one-dimensional copper bispyrazolate polymer reversibly and selectively absorbs a number small molecules; crystal structures anhydrous fully hydrated species, determined by powder diffraction methods, are markedly different despite their simple, fast, reversible interconversion.