Improving the low-temperature properties of alternative diesel fuels: Vegetable oil-derived methyl esters

作者: R. O. Dunn , M. W. Shockley , M. O. Bagby

DOI: 10.1007/BF02517978

关键词: Cold filter plugging pointOrganic chemistryDiesel fuelWinterizationChemistryBiodieselPetroleum productSoybean oilVegetable oilPour point

摘要: This work explores near-term approaches for improving the low-temperature properties of triglyceride oil-derived fuels direct-injection compression-ignition (diesel) engines. Methyl esters from transesterified soybean oil were evaluated as a neat fuel and in blends with petroleum middle distillates. Winterization showed that cloud point (CP) methyl soyate may be reduced to −16°C. Twelve cold-flow additives marketed distillates tested by standard methodologies, including CP, pour (PP), kinematic viscosity, cold filter plugging (CFPP), flow test (LTFT). Results additive treatment significantly improves PP distillate/methyl ester blends; however, do not greatly affect CP or viscosity. Both CFPP LTFT nearly linear functions result compares well earlier studies untreated blends. In particular, proved capable reducing neart 5–6°C. supports research on properties; is, ester-based diesel should continue focus CP.

参考文章(16)
M.L. McMillan, E.G. Barry, FUEL AND VEHICLE EFFECTS ON LOW-TEMPERATURE OPERATION OF DIESEL VEHICLES--THE 1981 CRC FIELD TEST SAE International Congress and Exposition. ,(1983) , 10.4271/830594
Alton Edward Bailey, Melting and solidification of fats Interscience Publishers. ,(1950)
Kyle W. Scholl, Spencer C. Sorenson, Combustion of Soybean Oil Methyl Ester in a Direct Injection Diesel Engine International Congress & Exposition. ,(1993) , 10.4271/930934
John E. Chandler, The Effect of Cold Flow Additives on Low Temperature Operability of Diesel Fuels International Fuels & Lubricants Meeting & Exposition. ,(1992) , 10.4271/922186
Alain Heraud, Bernard Pouligny, How does a cloud point diesel fuel additive work joint international conference on information sciences. ,vol. 153, pp. 378- 391 ,(1992) , 10.1016/0021-9797(92)90329-K
C. E. Goering, A. W. Schwab, M. J. Daugherty, E. H. Pryde, A. J. Heakin, Fuel properties of eleven vegetable oils Transactions of the ASABE. ,vol. 25, pp. 1472- 1477 ,(1982) , 10.13031/2013.33748
R. O. Dunn, M. O. Bagby, Low-temperature properties of triglyceride-based diesel fuels : transesterified methyl esters and petroleum middle distillate/ester blends Journal of the American Oil Chemists' Society. ,vol. 72, pp. 895- 904 ,(1995) , 10.1007/BF02542067
D.H.M. Beiny, J.W. Mullin, K. Lewtas, Crystallization of n-dotriacontane from hydrocarbon solution with polymeric additives Journal of Crystal Growth. ,vol. 102, pp. 801- 806 ,(1990) , 10.1016/0022-0248(90)90845-C
L. G. Schumacher, S. C. Borgelt, W. G. Hires, Fueling a Diesel Engine with Methyl-ester Soybean Oil Applied Engineering in Agriculture. ,vol. 11, pp. 37- 40 ,(1995) , 10.13031/2013.25714