Theoretical considerations on the performance of electrochemical flow-through detectors

作者: H.B. Hanekamp , H.J. Van Nieuwkerk

DOI: 10.1016/S0003-2670(01)84395-6

关键词: ElectrochemistryChemistryOptoelectronicsFlow (mathematics)DetectorAnalytical chemistryElectrodeLimiting currentSpectroscopyBiochemistryEnvironmental chemistry

摘要: Abstract A survey of the equations on limiting current in electrochemical flow-through cells is presented. For voltammetric detectors, a generalized equation for given. The conditions to be considered designing an detector optimal signal-to-noise ratios are outlined tubular, thin-layer, wall-jet and disk electrodes.

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