High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide

作者: Kai-xuan SHENG , Yu-xi XU , Chun LI , Gao-quan SHI

DOI: 10.1016/S1872-5805(11)60062-0

关键词: ElectrochemistryOxideX-ray photoelectron spectroscopyGrapheneNanotechnologySupercapacitorGraphene oxide paperRaman spectroscopyMaterials scienceScanning electron microscope

摘要: Abstract Three-dimensional self-assembled graphene hydrogels (SGHs) have been fabricated by chemical reduction of oxide (GO) with sodium ascorbate. The SGHs were characterized scanning electron microscopy, rheological tests, electrical conductivity measurements, X-ray photoelectron spectroscopy, diffraction, and Raman spectroscopy. Results indicate that the GO promotes assembly sheets. are electrically conductive (1 S·m −1 ) mechanically strong exhibit excellent electrochemical performance. In 1 mol·L aqueous solution H 2 SO 4 , specific capacitance was measured to be about 240 F·g at a discharge current density 1.2 A·g .

参考文章(46)
Jianfeng Shen, Yizhe Hu, Chen Li, Chen Qin, Min Shi, Mingxin Ye, Layer-by-Layer Self-Assembly of Graphene Nanoplatelets Langmuir. ,vol. 25, pp. 6122- 6128 ,(2009) , 10.1021/LA900126G
Jiali Zhang, Haijun Yang, Guangxia Shen, Ping Cheng, Jingyan Zhang, Shouwu Guo, Reduction of graphene oxide vial-ascorbic acid Chem. Commun.. ,vol. 46, pp. 1112- 1114 ,(2010) , 10.1039/B917705A
Dmitriy A. Dikin, Richard D. Piner, Rodney S. Ruoff, Inhwa Jung, Tunable electrical conductivity of individual graphene oxide sheets reduced at "low" temperatures. Nano Letters. ,vol. 8, pp. 4283- 4287 ,(2008) , 10.1021/NL8019938
Yiqing Sun, Chun Li, Yuxi Xu, Hua Bai, Zhiyi Yao, Gaoquan Shi, Chemically converted graphene as substrate for immobilizing and enhancing the activity of a polymeric catalyst Chemical Communications. ,vol. 46, pp. 4740- 4742 ,(2010) , 10.1039/C001635G
Jonathan K. Wassei, Richard B. Kaner, Graphene, a promising transparent conductor Materials Today. ,vol. 13, pp. 52- 59 ,(2010) , 10.1016/S1369-7021(10)70034-1
EunJoo Yoo, Tatsuhiro Okata, Tornoki Akita, Masanori Kohyama, Junji Nakamura, Itaru Honma, Enhanced Electrocatalytic Activity of Pt Subnanoclusters on Graphene Nanosheet Surface Nano Letters. ,vol. 9, pp. 2255- 2259 ,(2009) , 10.1021/NL900397T
A Chenite, M Buschmann, D Wang, C Chaput, NJCP Kandani, Rheological characterisation of thermogelling chitosan/glycerol-phosphate solutions Carbohydrate Polymers. ,vol. 46, pp. 39- 47 ,(2001) , 10.1016/S0144-8617(00)00281-2
Longhua Tang, Ying Wang, Yueming Li, Hongbing Feng, Jin Lu, Jinghong Li, Preparation, Structure, and Electrochemical Properties of Reduced Graphene Sheet Films Advanced Functional Materials. ,vol. 19, pp. 2782- 2789 ,(2009) , 10.1002/ADFM.200900377
Dongxing Yang, Aruna Velamakanni, Gülay Bozoklu, Sungjin Park, Meryl Stoller, Richard D. Piner, Sasha Stankovich, Inhwa Jung, Daniel A. Field, Carl A. Ventrice, Rodney S. Ruoff, Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy Carbon. ,vol. 47, pp. 145- 152 ,(2009) , 10.1016/J.CARBON.2008.09.045
C. Lee, X. Wei, J. W. Kysar, J. Hone, Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Science. ,vol. 321, pp. 385- 388 ,(2008) , 10.1126/SCIENCE.1157996