Modular Self-Assembly and Dynamics in Coordination Star Polymer Glasses: New Media for Ion Transport

摘要: We report modulation of the self-assembled microstructure and dynamics Coordination Star Polymer (CSP) materials their utilization for ion transport. Series CSPs with identical cores but varying arm lengths were synthesized via a convergent route. The assembled structures exhibit glassy nature short-range structural order while long-range disorder dynamic polymer domains. hierarchical structure mechanical properties are tunable by controlling size CSP corona. Glassy CPSs domain employed as matrix transport alkali metal cations, solvent free Li+ conductivities optimized glass found to be comparable those well known organic electrolytes. Further, we characterized that transporting behavior in glasses is strongly correlated ordering local dynamics. soft was explored improve solid–solid interfac...