Effect of preparation method on the valence state and encirclement of copper exchange ions in mordenites
作者： Y.M. Zhukov , A. Yu. Efimov , M.G. Shelyapina , V. Petranovskii , E.V. Zhizhin
DOI: 10.1016/J.MICROMESO.2015.12.058
关键词: Copper 、 Oxidation state 、 Ion 、 Chemistry 、 Analytical chemistry 、 Preparation method 、 Atomic ratio 、 Spectral line 、 Valence (chemistry) 、 Inorganic chemistry 、 X-ray photoelectron spectroscopy
摘要: Abstract Samples of mordenites with variable Si/Al atomic ratio and different counter-ions were exchanged copper ions by two methods – the conventional treatment in water solution microwave-assisted procedure. The zeolite-solution concentration kept equal for both procedures. We report on results XRD, TGA XPS studies. analysis confirms that despite observed differences spectra samples are the +2 oxidation state. preparation method influences content surrounding, but does not change electronic state ions.
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