The two-photon spectrum of toluene vapor

作者: R. Vasudev , J.C.D. Brand

DOI: 10.1016/0301-0104(79)80021-X

关键词: Intensity (physics)SpectroscopyChemistryMolecular electronic transitionFluorobenzeneTensorTolueneTwo-photon excitation microscopyMolecular physicsNuclear magnetic resonanceExcitation

摘要: Abstract The two-photon excitation spectrum of toluene-h8 and toluene-d8 vapor has been recorded under low resolution (1 cm−1) in the region S1 ← S0 (1B2 1A1) transition. Although electronic transition is formally allowed spectroscopy, a large fraction intensity exists subsystem induced by out-of-phase CC stretching vibration ν14 (b2). Band contours associated with each two assigned tensor components are identified partially analyzed comparison fluorobenzene.

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