作者: R. Vasudev , J.C.D. Brand
DOI: 10.1016/0301-0104(79)80021-X
关键词: Intensity (physics) 、 Spectroscopy 、 Chemistry 、 Molecular electronic transition 、 Fluorobenzene 、 Tensor 、 Toluene 、 Two-photon excitation microscopy 、 Molecular physics 、 Nuclear magnetic resonance 、 Excitation
摘要: Abstract The two-photon excitation spectrum of toluene-h8 and toluene-d8 vapor has been recorded under low resolution (1 cm−1) in the region S1 ← S0 (1B2 1A1) transition. Although electronic transition is formally allowed spectroscopy, a large fraction intensity exists subsystem induced by out-of-phase CC stretching vibration ν14 (b2). Band contours associated with each two assigned tensor components are identified partially analyzed comparison fluorobenzene.