Preparation and application of poly(zwitterionic ionic liquid) to enhance the photocatalytic activity of TiO2

作者: Luanluan Zhang , Jia Du , Ting Ran , Hejun Gao , Yunwen Liao

DOI: 10.1007/S10853-016-9999-Z

关键词: Chemical engineeringMoleculeDegradation (geology)Materials scienceMethyl orangePhotocatalysisNanoscopic scaleOrganic chemistrySpecific surface areaRhodamine BIonic liquid

摘要: A novel composite material PIL@TiO2 was synthesized by sol–gel method using zwitterionic ionic liquid (1-(3-sulfonic group) propyl-3-ethylimidazole). TiO2 uniformly loaded on PIL (poly(1-(3-sulfonic propyl-3-ethylimidazole)). The large specific surface area, unique microspore structure, negative effect, and synergistic effect were caused PIL. can effectively improve the separation efficiency of electron–hole photogeneration. pair ·OH play an important role in photo-degradation. structure dye molecule is also influencing factor for degradation capacity. After five cycle experiments, still exhibited excellent photocatalytic to molecules its better than that P-25 (nanoscale TiO2) methyl orange Rhodamine B solutions.

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