In situ measurements of electrode potentials of anode and cathode in organic electrochromic devices

作者: Shota Tsuneyasu , Yuichi Watanabe , Kazuki Nakamura , Norihisa Kobayashi

DOI: 10.1016/J.SOLMAT.2017.01.035

关键词: Standard hydrogen electrodeAbsolute electrode potentialElectrode potentialWorking electrodeInorganic chemistryQuinhydrone electrodeSaturated calomel electrodeNanotechnologyReference electrodeMaterials sciencePalladium-hydrogen electrode

摘要: Abstract The in situ electrode potentials of anodes and cathodes electrochromic (EC) devices were investigated. solution-based 2-electrode EC device was fabricated with electrolyte solutions containing anodic cathodic molecules. electrochemical reaction a controlled by the when electroactive molecules smaller concentrations used. In addition, showing less activity subjected to larger overpotential under application driving voltage, leading promotion redox at electrode. results showed that spontaneously regulated facilitate both reactions. It is very important know potential each order understand detail device.

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