Intramolecularly Coordinated Telluroxane Clusters and Polymers
作者： Jens Beckmann , Jens Bolsinger , Andrew Duthie
关键词: Hydrolysis 、 Chemistry 、 Reaction conditions 、 Stoichiometry 、 Alkali metal 、 Crystallography 、 Tellurium 、 Inorganic chemistry 、 Polymer 、 Hydrochloric acid 、 Chloride
摘要: The stoichiometrically controlled chlorination of the diarylditelluride (8‐Me2NC10H6Te) 2 with SO2Cl2 afforded the aryltellurinyl chloride 8‐Me2NC10H6TeCl (1) and the aryltellurium trichloride 8‐Me2NC10H6TeCl3 (2). Alternatively, 1 was obtained by the reaction of the aryltellurenyl diethyldithiacarbamate 8‐Me2NC10H6Te (S2CNEt2) with hydrochloric acid. The base hydrolysis of 2 provided the novel telluroxanes (8‐Me2NC10H6Te) 2OCl4 (3),(8‐Me2NC10H6Te) 6O5Cl8 (4),(8‐Me2NC10H6Te) 6O8Cl2 (5),[(8‐Me2NC10H6Te) 2O3] n (6) …
sci-hub.se 参考文章(34)
Raouf El-Mallawany, Tellurite glasses: Part 2. Anelastic, phase separation, Debye temperature and thermal properties Materials Chemistry and Physics. ,vol. 60, pp. 103- 131 ,(1999) , 10.1016/S0254-0584(99)00082-6
Jens Beckmann, Dainis Dakternieks, Andrew Duthie, François Ribot, Markus Schürmann, Naomi A. Lewcenko, New insights into the structures of diorganotellurium Oxides. The first polymeric diorganotelluroxane[(p-MeOC6H4)2TEO]n Organometallics. ,vol. 22, pp. 3257- 3261 ,(2003) , 10.1021/OM021024C
Kriti Srivastava, Sagar Sharma, Harkesh B. Singh, Udai P. Singh, Ray J. Butcher, Hydrolysis of 2-phenylazophenyltellurium trihalides: isolation of an unprecedented homometallic, discrete heptanuclear organotellurium oxide cluster Chemical Communications. ,vol. 46, pp. 1130- 1132 ,(2010) , 10.1039/B921785A
Saija C. Menon, Harkesh B. Singh, John M. Jasinski, Jerry P. Jasinski, Ray J. Butcher, INTRAMOLECULARLY COORDINATED LOW-VALENT ORGANOTELLURIUM COMPLEXES DERIVED FROM 1-(DIMETHYLAMINO)NAPHTHALENE Organometallics. ,vol. 15, pp. 1707- 1712 ,(1996) , 10.1021/OM950841S
Nathaniel W. Alcock, W. David Harrison, Secondary bonding. Part 7. Crystal and molecular structures of diphenyltellurium dichloride and phenyltellurium trichloride Journal of The Chemical Society-dalton Transactions. pp. 251- 255 ,(1982) , 10.1039/DT9820000251
Jens Beckmann, Pamela Finke, Malte Hesse, Burkhard Wettig, Wohldefinierte Stibonsäuren und Tellurinsäuren Angewandte Chemie. ,vol. 120, pp. 10130- 10133 ,(2008) , 10.1002/ANGE.200803997
J. C. McLaughlin, S. L. Tagg, J. W. Zwanziger, The Structure of Alkali Tellurite Glasses Journal of Physical Chemistry B. ,vol. 105, pp. 67- 75 ,(2001) , 10.1021/JP0025779
Raouf El-Mallawany, Tellurite glasses. Part 1. Elastic properties Materials Chemistry and Physics. ,vol. 53, pp. 93- 120 ,(1998) , 10.1016/S0254-0584(97)02041-5
Jens Beckmann, Jens Bolsinger, Andrew Duthie, New Insights into the Formation and Structure of Diaryl Tritellurides Organometallics. ,vol. 28, pp. 4610- 4612 ,(2009) , 10.1021/OM900494D
A.P. Mirgorodsky, T. Merle-Méjean, J.-C. Champarnaud, P. Thomas, B. Frit, Dynamics and structure of TeO2 polymorphs : Model treatment of paratellurite and tellurite; Raman scattering evidence for new γ- and δ-phases Journal of Physics and Chemistry of Solids. ,vol. 61, pp. 501- 509 ,(2000) , 10.1016/S0022-3697(99)00263-2