作者: Toshiyuki Tanaka , Munekazu Iinuma , Kaoru Yuki , Yuko Fujii , Mizuo Mizuno
DOI: 10.1016/0031-9422(92)80055-J
关键词: Stereochemistry 、 Dihydrochalcone 、 Bark 、 Pongamia 、 Spectral analysis 、 Flavonoid 、 Chalcone 、 Flavanone 、 Chemistry
摘要: Abstract Further investigation of the flavonoid constituents Pongamia pinnata from Japan resulted in isolation 18 compounds including nine new ones, ponganones III–XI, its root bark. The structures were determined to be (2 S )-3′,4′-dimethoxy-6″,6″-dimethylpyrano[2″,3″:7,8]-flavanone (III), )-6,3′,4′-trimethoxy-6″,6″-dimethylpyrano[2″,3″:7,8]-flavanone (IV), )-7-methoxy-6- O -γ,γ-dimethylallyl-3′,4′-methylenedioxyflavanone (V), 2′-hydroxy-3,4,5′-trimethoxy-6″,6″-dimethylpyrano[2″,3″:4′,3′]chalcone (VI), 2′,4′-dimethoxy-3,4-methylenedioxydioxydihydrochalcone (VII), 2′,5′,β-trimethoxy-3,4-methylenedioxy-6″,6″-dimethylpyrano[2″,3″:4′,3′]dihydrochalcone (VIII), 2,β-dimethoxy-3,4-methylenedioxy-furano[2″,3″:4′,3′]-dihydrochalcone (IX), β-hydroxy-2′,4′,6′-trimethoxy-3,4-methylenedioxychalcone (X) and 3-methoxy-furano-[2″,3″:7,6]flavone (XI), respectively, by means spectral analysis synthesis.