KINETIC PARAMETERS AFFECTING THE ALKALI-CATALYZED TRANSESTERIFICATION PROCESS OF USED OLIVE OIL
作者： M. Pilar Dorado , Evaristo Ballesteros , Martin Mittelbach , Francisco J. López
DOI: 10.1021/EF034088O
关键词: Distilled water 、 Solubility 、 Chemistry 、 Glyceride 、 Yield (chemistry) 、 Glycerol 、 Catalysis 、 Methanol 、 Organic chemistry 、 Nuclear chemistry 、 Transesterification
摘要: In this study, chemical parameters involved in waste olive oil transesterification were investigated and optimized. Better results obtained using KOH methanol instead of NaOH ethanol, which decreases rates. The presence above or below the optimum quantity ester yield because soaps unreacted glycerides, respectively. Settling at ambient temperature under 25 °C increases difficulty glycerol separation a conflict between solubility low temperatures. This could be solved by increasing settling time for settling. summary, reaction was optimized 1.26% KOH, 12% methanol, 1 min stirring, with 90 pour-off time, 11.38% distilled water volume to purify ester, drying over 0.5% Na2SO4. Losses esters during washing process less than 4%. 94%. small prese...
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D. L. Purcell, B. T. McClure, J. McDonald, Hemendra N. Basu, Transient testing of soy methyl ester fuels in an indirect injection, compression ignition engine Journal of the American Oil Chemists' Society. ,vol. 73, pp. 381- 388 ,(1996) , 10.1007/BF02523435
B. Freedman, E. H. Pryde, T. L. Mounts, Variables affecting the yields of fatty esters from transesterified vegetable oils Journal of the American Oil Chemists' Society. ,vol. 61, pp. 1638- 1643 ,(1984) , 10.1007/BF02541649
C. Peterson, D. Reece, Emissions Characteristics of Ethyl and Methyl Ester of Rapeseed Oil Compared with Low Sulfur Diesel Control Fuel in a Chassis Dynamometer Test of a Pickup Truck Transactions of the ASABE. ,vol. 39, pp. 805- 816 ,(1996) , 10.13031/2013.27564
M. J. Nye, T. W. Williamson, W. Deshpande, J. H. Schrader, W. H. Snively, T. P. Yurkewich, C. L. French, Conversion of used frying oil to diesel fuel by transesterification: preliminary tests Journal of the American Oil Chemists' Society. ,vol. 60, pp. 1598- 1601 ,(1983) , 10.1007/BF02666593
K. McDonnell, S. Ward, J. J. Leahy, P. McNulty, Properties of rapeseed oil for use as a diesel fuel extender Journal of the American Oil Chemists' Society. ,vol. 76, pp. 539- 543 ,(1999) , 10.1007/S11746-999-0001-Y
M. P. Dorado, E. Ballesteros, J. M. Arnal, J. Gómez, F. J. López Giménez, Testing Waste Olive Oil Methyl Ester as a Fuel in a Diesel Engine Energy & Fuels. ,vol. 17, pp. 1560- 1565 ,(2003) , 10.1021/EF0202485
P. De Filippis, C. Giavarini, M. Scarsella, M. Sorrentino, Transesterification processes for vegetable oils: A simple control method of methyl ester content Journal of the American Oil Chemists' Society. ,vol. 72, pp. 1399- 1404 ,(1995) , 10.1007/BF02546218
M. Mittelbach, H. Enzelsberger, Transesterification of heated rapeseed oil for extending diesel fuel Journal of the American Oil Chemists' Society. ,vol. 76, pp. 545- 550 ,(1999) , 10.1007/S11746-999-0002-X
Yuji Shimada, Yomi Watanabe, Taichi Samukawa, Akio Sugihara, Hideo Noda, Hideki Fukuda, Yoshio Tominaga, Conversion of vegetable oil to biodiesel using immobilized Candida antarctica lipase Journal of the American Oil Chemists' Society. ,vol. 76, pp. 789- 793 ,(1999) , 10.1007/S11746-999-0067-6
Filiz Karaosmanoǧlu, K. Barış Cıǧızoǧlu, Melek Tüter, Serap Ertekin, Investigation of the Refining Step of Biodiesel Production Energy & Fuels. ,vol. 10, pp. 890- 895 ,(1996) , 10.1021/EF9502214