Preparation and crystal structure of the addition compound MeLi·U[OCH(CMe3)2]4, a compound with a uranium to carbon σ-bond

作者： Joanne L. Stewart , Richard A. Andersen

关键词: Crystal structure 、 Crystallography 、 Methyl group 、 Chemistry 、 Square pyramidal molecular geometry 、 Lithium atom 、 Ligand 、 Stereochemistry 、 Molecule 、 Uranium 、 Alkoxide 、 Molecular medicine

摘要: Reaction of MeLi and U[OCH(CMe3)2]4 gives the addition compound, LiU(Me)[OCH(CMe3)2]4 which in solid state has a geometry based upon square pyramidal uranium with apical site occupied by methyl group four basal sites being oxygen atoms alkoxide ligand, two form bridges to lithium atom.