Selective adsorption of gold ions from complex system using oxidized multi-walled carbon nanotubes

作者: Huda A. Shaheen , Hadi M. Marwani , Ezzat M. Soliman

DOI: 10.1016/J.MOLLIQ.2015.09.040

关键词: AdsorptionLangmuir adsorption modelAqueous solutionInorganic chemistrySelective adsorptionCarbon nanotubeNitric acidMetal ions in aqueous solutionChemistryCarbon

摘要: Abstract The selective adsorption and removal of Au(III) ions using oxidized multi-walled carbon nanotubes from aqueous solutions containing different metal were studied. Characterization studies showed that MWCNTs by the concentrated nitric acid under normal laboratory conditions. study results only could be adsorbed completely complex system other at pH 2.0, within a few minutes ambient temperature. Also, interfering effect may co-exist with in was explored, no sign interference for nanotube surface. studied equilibrium found to follow Langmuir model, kinetically obey pseudo-second order kinetic model. capacity obtained 62.3 mg g− 1, which is higher than any reported value. Finally, real environmental water samples had high affinity selectivity used successfully solutions.

参考文章(42)
Qiong Li, Jingang Yu, Fang Zhou, Xinyu Jiang, Synthesis and characterization of dithiocarbamate carbon nanotubes for the removal of heavy metal ions from aqueous solutions Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 482, pp. 306- 314 ,(2015) , 10.1016/J.COLSURFA.2015.06.034
A. De Luca, M. T. Cole, R. H. Hopper, S. Boual, J. H. Warner, A. R. Robertson, S. Z. Ali, F. Udrea, J. W. Gardner, W. I. Milne, Enhanced spectroscopic gas sensors using in-situ grown carbon nanotubes Applied Physics Letters. ,vol. 106, pp. 194101- ,(2015) , 10.1063/1.4921170
Mohammad Behbahani, Azam Aliakbari, Mostafa M Amini, Ahmad S Behbahani, Fariborz Omidi, None, Synthesis and characterization of diphenylcarbazide-siliceous mesocellular foam and its application as a novel mesoporous sorbent for preconcentration and trace detection of copper and cadmium ions RSC Advances. ,vol. 5, pp. 68500- 68509 ,(2015) , 10.1039/C5RA10240E
C. Souza, D. Majuste, M.S.S. Dantas, V.S.T. Ciminelli, Selective adsorption of gold over copper cyanocomplexes on activated carbon Hydrometallurgy. ,vol. 147, pp. 188- 195 ,(2014) , 10.1016/J.HYDROMET.2014.05.017
Irving Langmuir, THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM. Journal of the American Chemical Society. ,vol. 40, pp. 1361- 1403 ,(1918) , 10.1021/JA02242A004
Mohammad Behbahani, Fatemeh Najafi, Mostafa M Amini, Omid Sadeghi, Akbar Bagheri, Parmoon Ghareh Hassanlou, None, Solid phase extraction using nanoporous MCM-41 modified with 3,4-dihydroxybenzaldehyde for simultaneous preconcentration and removal of gold(III), palladium(II), copper(II) and silver(I) Journal of Industrial and Engineering Chemistry. ,vol. 20, pp. 2248- 2255 ,(2014) , 10.1016/J.JIEC.2013.09.057
K. R. Hall, L. C. Eagleton, Andreas Acrivos, Theodore Vermeulen, Pore- and Solid-Diffusion Kinetics in Fixed-Bed Adsorption under Constant-Pattern Conditions Industrial & Engineering Chemistry Fundamentals. ,vol. 5, pp. 212- 223 ,(1966) , 10.1021/I160018A011
A. Ramesh, H. Hasegawa, W. Sugimoto, T. Maki, K. Ueda, Adsorption of gold(III), platinum(IV) and palladium(II) onto glycine modified crosslinked chitosan resin Bioresource Technology. ,vol. 99, pp. 3801- 3809 ,(2008) , 10.1016/J.BIORTECH.2007.07.008