Supramolecular Microgels Fabricated from Supramonomers
作者： Qiao Song , Yongfeng Gao , Jiang-Fei Xu , Bo Qin , Michael J. Serpe
DOI: 10.1021/ACSMACROLETT.6B00592
关键词: Nanotechnology 、 Supramolecular chemistry 、 Moiety 、 Acrylate 、 Degradation kinetics 、 Copolymer 、 Materials science 、 Structure and function
摘要: This letter describes a new method for fabricating supramolecular microgels from supramonomers. To this end, we designed and assembled supramonomers with one acrylate moiety on each end the basis of noncovalent host–guest interactions, which could be utilized as cross-linker. Then were fabricated through copolymerization N-isopropylacrylamide (NIPAm). The not only showed temperature-responsive properties expected conventional PNIPAm-based but also exhibited stimuli-responsive degradable benefiting dynamic nature In addition, it was found that degradation kinetics related greatly to structure microgels, providing way tune microgels. Various desired function are supposed facilely It is ant...
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