t-BuXPhos: a highly efficient ligand for Buchwald–Hartwig coupling in water

作者: Patrick Wagner , Maud Bollenbach , Christelle Doebelin , Frédéric Bihel , Jean-Jacques Bourguignon

DOI: 10.1039/C4GC00853G

关键词: Rapid accessCoupling (electronics)Organic synthesisChemistryCatalysisAqueous solutionLigandOrganic chemistryPollutionEnvironmental chemistry

摘要: A highly efficient, eco-friendly N-arylation was disclosed outspreading perspectives in green Buchwald–Hartwig reactions.

参考文章(69)
John F. Hartwig, Palladium‐Catalyzed Amination of Aryl Halides and Related Reactions ChemInform. ,vol. 34, pp. 1051- 1096 ,(2003) , 10.1002/0471212466.CH42
Xavier Sauvage, Albert Demonceau, Lionel Delaude, Imidazol(in)ium‐2‐carboxylates as N‐Heterocyclic Carbene Precursors for the Synthesis of Second Generation Ruthenium Metathesis Catalysts Advanced Synthesis & Catalysis. ,vol. 351, pp. 2031- 2038 ,(2009) , 10.1002/ADSC.200900422
Nicholas A. Isley, Fabrice Gallou, Bruce H. Lipshutz, Transforming Suzuki–Miyaura Cross-Couplings of MIDA Boronates into a Green Technology: No Organic Solvents Journal of the American Chemical Society. ,vol. 135, pp. 17707- 17710 ,(2013) , 10.1021/JA409663Q
Dinesh Kumar, Kapileswar Seth, Damodara N. Kommi, Srikant Bhagat, Asit K. Chakraborti, Surfactant micelles as microreactors for the synthesis of quinoxalines in water: scope and limitations of surfactant catalysis RSC Advances. ,vol. 3, pp. 15157- 15168 ,(2013) , 10.1039/C3RA41038B
Richard N. Butler, Anthony G. Coyne, Water: Nature’s Reaction Enforcer—Comparative Effects for Organic Synthesis “In-Water” and “On-Water” Chemical Reviews. ,vol. 110, pp. 6302- 6337 ,(2010) , 10.1021/CR100162C
Alan R Katritzky, Charles W Rees, Eric FV Scriven, None, Comprehensive heterocyclic chemistry II Pergamon. ,(1996)
Noemi Cabello-Sanchez, Ludovic Jean, Jacques Maddaluno, Marie-Claire Lasne, Jacques Rouden, Palladium-mediated N-arylation of heterocyclic diamines: insights into the origin of an unusual chemoselectivity. Journal of Organic Chemistry. ,vol. 72, pp. 2030- 2039 ,(2007) , 10.1021/JO062301I
Alex R. Muci, Stephen L. Buchwald, Practical Palladium Catalysts for C-N and C-O Bond Formation Topics in Current Chemistry. ,vol. 219, pp. 131- 209 ,(2002) , 10.1007/3-540-45313-X_5