Studying the Iodide Ion Solvation in Water–Dimethyl Sulfoxide Mixtures by the Method of Volta Potential Differences
作者： V. I. Parfenyuk , T. I. Chankina
关键词: Inorganic chemistry 、 Solvation 、 Bromide 、 Dimethyl sulfoxide 、 Chloride 、 Gibbs free energy 、 Electrochemistry 、 Chemistry 、 Sulfoxide 、 Iodide
摘要: Real and chemical thermodynamic parameters of resolvation the iodide ion in water–dimethyl sulfoxide mixtures at 298 K are determined by method Volta potential differences. The real parameters, as those chloride bromide ions earlier studied similar solvents positive, which is due to restructuring a surface layer solution/gas phase interface. An analysis energies shows that anions capable forming hydrogen bonds with proton-donor weakly solvated aprotic solvents.
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