Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand
作者： Bei-bei Tang , Heng Ma , Guan-zheng Li , Yue-bing Wang , Gulinazi Anwar
DOI: 10.1039/C3CE41034J
关键词: Molecular cluster 、 Stereochemistry 、 Luminescence 、 Crystallography 、 Schiff base 、 Ligand 、 Crystal structure 、 Chemistry
摘要: Two kinds of tetranuclear Zn(II) molecular clusters with the designed aroylhydrazone Schiff base ligand (H3333L), [Zn4(HL)4]·3(DMF)·3(H2O) (1) and [Zn4(HL)2(CH3COO)4]·2(DMF)·2(CH3OH) (2), have been synthesized studied. Molecular cluster 1 displayed a Zn4O4 boat-shaped core 2 presented discrete linear structure. The luminescent properties two investigated, which exhibit wide range photo-luminescence in different organic solvents.
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