Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms

作者: Mar Gómez-Gallego , Miguel A. Sierra

DOI: 10.1021/CR100436K

关键词: Reaction mechanismKinetic isotope effectComputational chemistryChemistryKinetic energy

摘要:

参考文章(536)
William D. McGhee, Frederick J. Hollander, Robert G. Bergman, C-H oxidative addition and reductive elimination reactions in a dinuclear iridium complex Journal of the American Chemical Society. ,vol. 110, pp. 8428- 8443 ,(1988) , 10.1021/JA00233A020
William D. Jones, Frank J. Feher, Comparative reactivities of hydrocarbon C-H bonds with a transition-metal complex Accounts of Chemical Research. ,vol. 22, pp. 91- 100 ,(1989) , 10.1021/AR00159A002
R. Martin Chin, Lingzhen Dong, Simon B. Duckett, Martin G. Partridge, William D. Jones, Robin N. Perutz, Control of .eta.2-coordination vs. carbon-hydrogen bond activation by rhodium: the role of aromatic resonance energies Journal of the American Chemical Society. ,vol. 115, pp. 7685- 7695 ,(1993) , 10.1021/JA00070A012
Faraj Abu-Hasanayn, Karsten Krogh-Jespersen, Alan S. Goldman, Theoretical Study of Primary and Secondary Deuterium Equilibrium Isotope Effects for H2 and CH4 Addition to trans-Ir(PR3)2(CO)X Journal of the American Chemical Society. ,vol. 115, pp. 8019- 8023 ,(1993) , 10.1021/JA00071A012
W. D. Jones, Conquering the Carbon-Hydrogen Bond Science. ,vol. 287, pp. 1942- 1943 ,(2000) , 10.1126/SCIENCE.287.5460.1942
Iwao Ojima, Tetsuo Kogure, Miyoko Kumagai, Shuji Horiuchi, Toshikazu Sato, Reduction of carbonyl compounds via hydrosilylation. 3. Asymmetric reduction of keto esters via hydrosilylation catalyzed by a rhodium complex with chiral phosphine ligands Journal of Organometallic Chemistry. ,vol. 122, pp. 83- 97 ,(1977) , 10.1016/S0022-328X(00)92750-5