Surface-mediated organometallic synthesis: preparation of osmium carbonyl clusters [Os5C(CO)14]2- and [Os10C(CO)24]2- on the basic magnesium oxide surface

作者: H. Henry Lamb , Anthony S. Fung , Patricia A. Tooley , Jose Puga , Theodore R. Krause

DOI: 10.1021/JA00204A007

关键词: OsmiumMetalCarbon monoxideChemistryHydrogenInorganic chemistryInfrared spectroscopySurface reactionMagnesium

摘要: Les complexes [Os 5 C(CO) 14 ] 2− et 10 24 sont prepares par reaction du melange CO-H 2 a la surface de [H OsCl 6 3 (CO) 12 adsorbes sur MgO

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