ASPHALTENE PRECIPITATION AND SOLVENT PROPERTIES OF CRUDE OILS

作者: J.S. BUCKLEY , G.J. HIRASAKI , Y. LIU , S. VON DRASEK , J-X. WANG

DOI: 10.1080/10916469808949783

关键词: Precipitation (chemistry)MineralogyAsphalteneFlocculationThermodynamicsSolventSolubilityLondon dispersion forceAsphaltene precipitationChemistryViscosity

摘要: ABSTRACT Improved prediction of the onset asphaltene precipitation may be achieved using refractive index (RI) to characterize crude oils and their mixtures with precipitants solvents. Experimental measurements RI for several precipitant n-heptane, are reported at ambient conditions. Theoretical developments described that will permit extension these observations reservoir conditions Measurements RJ have shown occurs a characteristic each oil/ combination, supporting premise is dominated by London dispersion interactions thus, can used predict precipitation. Reports in literature showing constant solvent-to-precipitant ratios provide additional confirmation The theory developed on assumption forces dominate aggregation asphaltenes. i...

参考文章(26)
Roberto Cimino, Sebastiano Correra, Alberto Del Bianco, Thomas P. Lockhart, Solubility and Phase Behavior of Asphaltenes in Hydrocarbon Media Asphaltenes. pp. 97- 130 ,(1995) , 10.1007/978-1-4757-9293-5_3
Allan F. M. Barton, CRC Handbook of Solubility Parameters and Other Cohesion Parameters Barton, A.F.M. <https://researchrepository.murdoch.edu.au/view/author/Barton, Allan.html> (2017) CRC Handbook of Solubility Parameters and Other Cohesion Parameters. Routledge as part of the Taylor and Francis group, New York.. ,(1983)
S.F. Kashou, R.E. Hobbs, N.E. Burke, Measurement and modeling of asphaltene precipitation Journal of Petroleum Technology; (USA). ,(1990)
Joel Henry Hildebrand, Robert L. Scott, The solubility of nonelectrolytes Dover Publication. ,(1964)
Irwin A. Wiehe, TWO-DIMENSIONAL SOLUBILITY PARAMETER MAPPING OF HEAVY OILS Petroleum Science and Technology. ,vol. 14, pp. 289- 312 ,(1996) , 10.1080/08843759608947572
A. Hirschberg, L.N.J. deJong, B.A. Schipper, J.G. Meijer, Influence of Temperature and Pressure on Asphaltene Flocculation Society of Petroleum Engineers Journal. ,vol. 24, pp. 283- 293 ,(1984) , 10.2118/11202-PA
Huanquan Pan, Abbas Firoozabadi, A Thermodynamic Micellization Model for Asphaltene Precipitation: Part I: Micellar Size and Growth SPE Production & Facilities. ,vol. 13, pp. 118- 127 ,(1998) , 10.2118/36741-PA
D.J. MacMillan, J.E. Tackett, M.A. Jessee, T.G. Monger-McClure, A unified approach to asphaltene precipitation: Laboratory measurement and modeling Journal of Petroleum Technology. ,vol. 47, pp. 788- 793 ,(1995) , 10.2118/28990-PA
Nancy E. Burke, Ronald E. Hobbs, Samir F. Kashou, Measurement and Modeling of Asphaltene Precipitation (includes associated paper 23831 ) Journal of Petroleum Technology. ,vol. 42, pp. 1440- 1446 ,(1990) , 10.2118/18273-PA
Sat Parkash, Speros Moschopedis, James Speight, Physical properties and surface characteristics of asphaltenes Fuel. ,vol. 58, pp. 877- 882 ,(1979) , 10.1016/0016-2361(79)90204-7