Biomimetic synthesis of titania with chitosan-mediated phase transformation at room temperature
作者： Yong Yan , Bo Hao , Ge Chen
DOI: 10.1039/C1JM11056J
关键词: Polymer 、 Phase (matter) 、 Chemical engineering 、 Rutile 、 Chitosan 、 Materials science 、 Cellulose 、 Anatase 、 Inorganic chemistry 、 Protonation 、 Biomimetic synthesis
摘要: We have demonstrated the glucan polymer-mediated syntheses of titania at room temperature, which is an energy-conserving and environmentally benign synthetic pathway. Wormhole-like particles (both rutile anatase) with high surface areas quasi-sphere-shaped (anatase) were obtained for chitosan, sodium alginate cellulose, respectively. Particularly, we observed phase transformation from anatase to in chitosan-mediated process; experimental results revealed a distinct dependence on protonation level amino groups chitosan. The suggest that different charged polymers strongly impact size, shape polymorph particles, might provide new insights into vitro bio-enabled formation pave way further studies transformations.
rsc.org
sci-hub.se 参考文章(17)
Matthew B. Dickerson, Kenneth H. Sandhage, Rajesh R. Naik, Protein- and peptide-directed syntheses of inorganic materials. Chemical Reviews. ,vol. 108, pp. 4935- 4978 ,(2008) , 10.1021/CR8002328
Holly J. Martin, Kirk H. Schulz, Joel D. Bumgardner, Keisha B. Walters, XPS study on the use of 3-aminopropyltriethoxysilane to bond chitosan to a titanium surface. Langmuir. ,vol. 23, pp. 6645- 6651 ,(2007) , 10.1021/LA063284V
Heather R. Luckarift, Matthew B. Dickerson, Kenneth H. Sandhage, Jim C. Spain, Rapid, room-temperature synthesis of antibacterial bionanocomposites of lysozyme with amorphous silica or titania. Small. ,vol. 2, pp. 640- 643 ,(2006) , 10.1002/SMLL.200500376
Matthew B. Dickerson, Sharon E. Jones, Ye Cai, Gul Ahmad, Rajesh R. Naik, Nils Kröger, Kenneth H. Sandhage, Identification and Design of Peptides for the Rapid, High-Yield Formation of Nanoparticulate TiO2 from Aqueous Solutions at Room Temperature Chemistry of Materials. ,vol. 20, pp. 1578- 1584 ,(2008) , 10.1021/CM071515T
Ge Chen, Min Li, Fan Li, Shaorui Sun, Dingguo Xia, Protein‐Mediated Synthesis of Nanostructured Titania with Different Polymorphs at Room Temperature Advanced Materials. ,vol. 22, pp. 1258- 1262 ,(2010) , 10.1002/ADMA.200902901
O CARP, Photoinduced reactivity of titanium dioxide Progress in Solid State Chemistry. ,vol. 32, pp. 33- 177 ,(2004) , 10.1016/J.PROGSOLIDSTCHEM.2004.08.001
Sarah L. Sewell, David W. Wright, Biomimetic Synthesis of Titanium Dioxide Utilizing the R5 Peptide Derived from Cylindrotheca fusiformis Chemistry of Materials. ,vol. 18, pp. 3108- 3113 ,(2006) , 10.1021/CM060342P
Michael P. Finnegan, Hengzhong Zhang, Jillian F. Banfield, Anatase Coarsening Kinetics under Hydrothermal Conditions As a Function of Ph and Temperature Chemistry of Materials. ,vol. 20, pp. 3443- 3449 ,(2008) , 10.1021/CM071057O
G. Iucci, M. Dettin, C. Battocchio, R. Gambaretto, C. Di Bello, G. Polzonetti, Novel immobilizations of an adhesion peptide on the TiO2 surface: An XPS investigation Materials Science and Engineering: C. ,vol. 27, pp. 1201- 1206 ,(2007) , 10.1016/J.MSEC.2006.09.038
Yanjun Jiang, Dong Yang, Lei Zhang, Lin Li, Qianyun Sun, Yufei Zhang, Jian Li, Zhongyi Jiang, None, Biomimetic synthesis of titania nanoparticles induced by protamine Dalton Transactions. pp. 4165- 4171 ,(2008) , 10.1039/B802745E