Kinetics and thermodynamics of formation of copper-dioxygen adducts: oxygenation of mononuclear copper(I) complexes containing tripodal tetradentate ligands
作者： Kenneth D. Karlin , Ning Wei , Bernhard Jung , Susan Kaderli , Pascal Niklaus
DOI: 10.1021/JA00074A015
关键词: Reaction rate constant 、 Transition metal dioxygen complex 、 Chemistry 、 Polymer chemistry 、 Kinetics 、 Stereochemistry 、 Tris 、 Adduct 、 Copper 、 Reaction mechanism 、 Amine gas treating
摘要: … of O2, we have been carrying out biomimetic Cu'„/CL reactivity … of the spectrum of the thermodynamically unstable 1:1 adduct [{(… No mononuclear 1:1 adduct or any other intermediate is …
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