Cobalt(I)-сatalyzed [6π+2π]-сycloadditions of 1,2-dienes to 1,3,5,7-cyclooctatetraene

作者: Vladimir A. D’yakonov , Gulnara N. Kadikova , Guzel F. Gazizullina , Leonard M. Khalilov , Usein M. Dzhemilev

DOI: 10.1016/J.TETLET.2015.02.127

关键词: CatalysisComputational chemistryPolymer chemistryCobalt(II) iodideCyclooctatetraeneCobaltChemistryHomogeneous catalysis

摘要: The reaction between 1,2-dienes and 1,3,5,7-cyclooctatetraene in the presence of multicomponent catalyst, CoI2/dppe/Zn/ZnI2 leads to selective formation (E)-bicyclo[4.2.2]deca-2,4,7-triene derivatives yields 65–85%.

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