Selective extraction of Pu(IV) by a calix[6]arene bearing hydroxamic groups. Application to bioassays

作者: B. Boulet , C. Bouvier-Capely , G. Cote , L. Poriel , C. Cossonnet

DOI: 10.1016/J.JALLCOM.2006.12.038

关键词: ActinideContext (language use)ChemistryMoleculeHydroxamic acidExtraction (chemistry)UraniumCalixareneLiquid–liquid extractionNuclear chemistry

摘要: This work falls within the context of general pattern individual monitoring workers exposed to a risk internal contamination with actinides. The aim is propose new procedure for analyzing Pu traces from urine media and in presence uranium. extractant molecule used calix[6]arene bearing hydroxamic acid functions. affinity this towards Pu(IV) U(VI) has been studied possibility separate both elements shown.

参考文章(9)
Françoise Arnaud-Neu, Volker Böhmer, Jean-François Dozol, Cordula Grüttner, Ralf A. Jakobi, Dagmar Kraft, Olivier Mauprivez, Hélène Rouquette, Marie-José Schwing-Weill, Nicole Simon, Walter Vogt, Calixarenes with diphenylphosphoryl acetamide functions at the upper rim. A new class of highly efficient extractants for lanthanides and actinides J. Chem. Soc., Perkin Trans. 2. pp. 1175- 1182 ,(1996) , 10.1039/P29960001175
B. Boulet, C. Bouvier‐Capely, C. Cossonnet, G. Cote, Solvent extraction of U(VI) by calix[6]arenes Solvent Extraction and Ion Exchange. ,vol. 24, pp. 319- 330 ,(2006) , 10.1080/07366290600646939
R.J. Taylor, I. May, A.L. Wallwork, I.S. Denniss, N.J. Hill, B.Ya. Galkin, B.Ya. Zilberman, Yu.S. Fedorov, The applications of formo- and aceto-hydroxamic acids in nuclear fuel reprocessing Journal of Alloys and Compounds. ,vol. 271, pp. 534- 537 ,(1998) , 10.1016/S0925-8388(98)00146-7
Koji Araki, Norifumi Hashimoto, Hideyuki Otsuka, Takeshi Nagasaki, Seiji Shinkai, Molecular Design of a Calix[6]arene-Based Super-Uranophile with C3 Symmetry. High UO22+ Selectivity in Solvent Extraction Chemistry Letters. ,vol. 1993, pp. 829- 832 ,(1993) , 10.1246/CL.1993.829
Seiji Shinkai, Hiroshi Koreishi, Kaori Ueda, Takashi Arimura, Osamu Manabe, Molecular design of calixarene-based uranophiles which exhibit remarkably high stability and selectivity Journal of the American Chemical Society. ,vol. 109, pp. 6371- 6376 ,(1987) , 10.1021/JA00255A023
Iain May, Robin J. Taylor, Iain S. Denniss, Geoff Brown, Andrew L. Wallwork, Nick J. Hill, Jeremy M. Rawson, Robert Less, Neptunium(IV) and uranium(VI) complexation by hydroxamic acids Journal of Alloys and Compounds. ,vol. 275-277, pp. 769- 772 ,(1998) , 10.1016/S0925-8388(98)00437-X
M. Amélia Santos, Estela Rodrigues, Margarida Gaspar, A cyclohexane-1,2-diyldinitrilotetraacetate tetrahydroxamate derivative for actinide complexation: synthesis and complexation studies Journal of the Chemical Society, Dalton Transactions. pp. 4398- 4402 ,(2000) , 10.1039/B007007F
J. C. HARDUIN, B. PELEAU, D. LEVAVASSEUR, Détermination analytique des actinides dans les milieux biologiques Radioprotection. ,vol. 31, pp. 229- 245 ,(1996) , 10.1051/RADIOPRO/1996016
P.W. Durbin, N. Jeung, S.J. Rodgers, P.N. Turowski, F.L. Weitl, D.L. White, K.N. Raymond, Removal of 238Pu(IV) from Mice by Poly-Catechoylate, -Hydroxamate or -Hydroxypyridinonate Ligands Radiation Protection Dosimetry. ,vol. 26, pp. 351- 358 ,(1989) , 10.1093/OXFORDJOURNALS.RPD.A080429