Fascinating inorganic/bioinorganic reaction mechanisms☆
作者： Rudi van Eldik
DOI: 10.1016/J.CCR.2007.02.004
关键词: High pressure 、 Reaction mechanism 、 Bioinorganic chemistry 、 Chemistry 、 Organic chemistry 、 Group (periodic table)
摘要: This review presents recent examples of mechanistic studies performed in our group on the activation NO and peroxides by Fe(III) complexes, from which fascinating reaction mechanisms area inorganic/bioinorganic chemistry evolved. The insight gained is based information obtained application low-temperature rapid-scan techniques, as well high pressure thermodynamic kinetic measurements through volume profiles could be constructed.
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