Primary ammonium/tertiary amine-mediated controlled ring opening polymerisation of amino acid N-carboxyanhydrides.
作者： Charlotte D. Vacogne , Helmut Schlaad
DOI: 10.1039/C5CC06905J
关键词: Polymer chemistry 、 End-group 、 Amino acid 、 Organic chemistry 、 Ring (chemistry) 、 Ammonium 、 Polymerization 、 Chemistry 、 Molar mass distribution 、 Tertiary amine 、 Molar mass
摘要: Stable commercial primary ammonium chlorides were combined with tertiary amines to initiate the controlled ring opening polymerisation of amino acid N-carboxyanhydrides yield polypeptides defined end group structure, predetermined molar mass and narrow distribution.
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