Spectral insights into microdynamics of thermoresponsive polymers from the perspective of two-dimensional correlation spectroscopy
作者： Sheng-tong Sun , Pei-yi Wu
DOI: 10.1007/S10118-017-1938-1
关键词: Lower critical solution temperature 、 Phase transition 、 Chemical physics 、 Thermoresponsive polymers in chromatography 、 Raman spectroscopy 、 Chemistry 、 Two-dimensional nuclear magnetic resonance spectroscopy 、 Analytical chemistry 、 Polymer 、 Spectral line 、 Infrared
摘要: Generalized two-dimensional correlation spectroscopy (2DCOS) and its derivate technique, perturbation moving window (PCMW), have found great potential in studying a series of physico-chemical phenomena stimuli-responsive polymeric systems. By spreading peaks along second dimension, 2DCOS can significantly enhance spectral resolution discern the sequence group dynamics applicable to various external perturbation-induced spectroscopic changes, especially infrared (IR), near-infrared (NIR) Raman spectroscopy. On basis synchronous power spectra changing, PCMW proves be powerful tool monitor complicated variations find transition points ranges. This article reviews recent work our research application thermoresponsive polymers, mainly focused on liquid crystalline polymers lower critical solution temperature (LCST)-type polymers. Details motions chain conformational changes upon thus elucidated at molecular level, which contribute understanding their phase nature.
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sci-hub.se 参考文章(57)
Wenlong Li, Peiyi Wu, Unusual thermal phase transition behavior of an ionic liquid and poly(ionic liquid) in water with significantly different LCST and dynamic mechanism Polymer Chemistry. ,vol. 5, pp. 5578- 5590 ,(2014) , 10.1039/C4PY00593G
Shigeaki Morita, Hideyuki Shinzawa, Roumiana Tsenkova, Isao Noda, Yukihiro Ozaki, Computational simulations and a practical application of moving-window two-dimensional correlation spectroscopy Journal of Molecular Structure. ,vol. 799, pp. 111- 120 ,(2006) , 10.1016/J.MOLSTRUC.2006.03.023
Mikhail Motornov, Yuri Roiter, Ihor Tokarev, Sergiy Minko, Stimuli-responsive nanoparticles, nanogels and capsules for integrated multifunctional intelligent systems Progress in Polymer Science. ,vol. 35, pp. 174- 211 ,(2010) , 10.1016/J.PROGPOLYMSCI.2009.10.004
Mirosław A. Czarnecki, Stefano Okretic, Heinz W. Siesler, Reorientation of Nematic Liquid-Crystals and Liquid-Crystalline Polymers in an Electric Field Studied by FT-IR Time-Resolved Spectroscopy and 2D-Correlation Analysis Journal of Physical Chemistry B. ,vol. 101, pp. 374- 380 ,(1997) , 10.1021/JP961588S
Debashish Roy, William L. A. Brooks, Brent S. Sumerlin, New directions in thermoresponsive polymers. Chemical Society Reviews. ,vol. 42, pp. 7214- 7243 ,(2013) , 10.1039/C3CS35499G
Zhangwei Wang, Hengjie Lai, Peiyi Wu, Influence of PIL segment on solution properties of poly(N-isopropylacrylamide)-b-poly(ionic liquid) copolymer: micelles, thermal phase behavior and microdynamics Soft Matter. ,vol. 8, pp. 11644- 11653 ,(2012) , 10.1039/C2SM26172C
Lei Hou, Kai Ma, Zesheng An, Peiyi Wu, Exploring the Volume Phase Transition Behavior of POEGA- and PNIPAM-Based Core–Shell Nanogels from Infrared-Spectral Insights Macromolecules. ,vol. 47, pp. 1144- 1154 ,(2014) , 10.1021/MA4021906
Boguslawa Czarnik-Matusewicz, Sylwia Pilorz, Lorna Ashton, Ewan W. Blanch, Potential pitfalls concerning visualization of the 2D results Journal of Molecular Structure. ,vol. 799, pp. 253- 258 ,(2006) , 10.1016/J.MOLSTRUC.2006.03.064
Yilu Guo, Bingjie Sun, Peiyi Wu, Phase Separation of Poly(vinyl methyl ether) Aqueous Solution: A Near-Infrared Spectroscopic Study Langmuir. ,vol. 24, pp. 5521- 5526 ,(2008) , 10.1021/LA7038398
Mengyin Wang, Shengtong Sun, Peiyi Wu, Spectral insight into intensity variations in phase-transition processes using two-dimensional correlation analysis. Applied Spectroscopy. ,vol. 64, pp. 1396- 1406 ,(2010) , 10.1366/000370210793561529