A stable germanone as the first isolated heavy ketone with a terminal oxygen atom
作者： Liangchun Li , Tomohide Fukawa , Tsukasa Matsuo , Daisuke Hashizume , Hiroyuki Fueno
DOI: 10.1038/NCHEM.1305
关键词: Double bond 、 Ketone 、 Chemistry 、 Oxygen 、 Group (periodic table) 、 Oxygen atom 、 Polymer chemistry 、 Stereochemistry 、 Monomer
摘要: Heavier analogues of ketones — containing a double bond between group 14 element and oxygen have so far not been isolated as stable compounds. Now, monomeric germanone with highly polarized Ge=O has isolated, stabilized by rigid bulky ligands.
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