New solid polymer electrolyte composites for water electrolysis
作者： P. Millet , M. Pineri , R. Durand
DOI: 10.1007/BF01062295
关键词: Composite material 、 Noble metal 、 Electrolyte 、 Electrolysis of water 、 Electrolysis 、 Microprobe 、 Scanning electron microscope 、 Materials science 、 Electrochemistry 、 Polymer
摘要: A new procedure for the preparation of SPE-electrocatalyst composites has been developed. In this procedure, noble metal cationic species are chemically reduced within a solid polymer electrolyte. The metallic particles not homogeneously distributed across SPE thickness but predominate near its surfaces. structure and distribution precipitates, along membrane have investigated by scanning electron microprobe analysis transmission microscopy. Application to water electrolysis performed using Nafion membranes platinum-group electrocatalysts. prepared according present good electrochemical properties, low catalyst loadings, long-time stability high energetic efficiencies.
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sci-hub.se 参考文章(13)
Richard S. Yeo, Richard P. Buck, Proceedings of the Symposium on Ion Exchange--Transport and Interfacial Properties Electrochemical Society. ,(1981)
Peter Beutler, Heinz Gamsjäger, Preparation and ultraviolet–visible spectrum of hexa-aquairidium(III) Journal of The Chemical Society, Chemical Communications. pp. 554- 555 ,(1976) , 10.1039/C39760000554
Hiroshi Nakajima, Yoshio Takakuwa, Hirokazu Kikuchi, Keikichi Fujikawa, Hideaki Kita, Metal electrodes bonded on solid polymer electrolyte membranes (SPE)—IV. Morphological features and electrical resistance of Pt- and Au-SPE electrodes Electrochimica Acta. ,vol. 32, pp. 791- 798 ,(1987) , 10.1016/0013-4686(87)85111-3
A. Michas, J.M. Kelly, R. Durand, M. Pineri, J.M.D. Coey, Preparation, characterization and catalytic properties of perfluorosulfonated ion-exchange membranes containing surface-concentrated, hydrated ruthenium oxide particles Journal of Membrane Science. ,vol. 29, pp. 239- 257 ,(1986) , 10.1016/S0376-7388(00)81263-6
H TAKENAKA, E TORIKAI, Y KAWAMI, N WAKABAYASHI, Solid polymer electrolyte water electrolysis International Journal of Hydrogen Energy. ,vol. 7, pp. 397- 403 ,(1982) , 10.1016/0360-3199(82)90050-7
Kingo Itaya, Hideyuki Takahashi, Isamu Uchida, Electrodeposition of Pt ultramicroparticles in Nafion films on glassy carbon electrodes Journal of Electroanalytical Chemistry. ,vol. 208, pp. 373- 382 ,(1986) , 10.1016/0022-0728(86)80544-7
H. Kita, F. Fujikawa, H. Nakajima, Metal electrodes bonded on solid polymer electrolyte membranes (SPE)—II. The polarization resistance of Pt-Nafion electrode Electrochimica Acta. ,vol. 29, pp. 1721- 1724 ,(1984) , 10.1016/0013-4686(84)89017-9
Akiko Katayama-Aramata, Hiroshi Nakajima, Keikichi Fujikawa, Hideaki Kita, Metal electrodes bonded on solid polymer electrolyte membranes (SPE)—The behaviour of platinum bonded on SPE for hydrogen and oxygen electrode processes Electrochimica Acta. ,vol. 28, pp. 777- 780 ,(1983) , 10.1016/0013-4686(83)85146-9
P. W. T. Lu, S. Srinivasan, Advances in water electrolysis technology with emphasis on use of the solid polymer electrolyte Journal of Applied Electrochemistry. ,vol. 9, pp. 269- 283 ,(1979) , 10.1007/BF01112480
M.H. Miles, E.A. Klaus, B.P. Gunn, J.R. Locker, W.E. Serafin, S. Srinivasan, The oxygen evolution reaction on platinum, iridium, ruthenium and their alloys at 80°C in acid solutions Electrochimica Acta. ,vol. 23, pp. 521- 526 ,(1978) , 10.1016/0013-4686(78)85030-0