Bridged ferrocenes—II
作者： T.H. Barr , W.E. Watts
DOI: 10.1016/S0040-4020(01)96343-4
关键词: Crystallography 、 Ferrocene 、 Torsion (mechanics) 、 Molecular geometry 、 Cyclopentadienyl complex 、 Chemistry 、 Spectral properties 、 Computational chemistry
摘要: Abstract The extent to which the molecular geometry and conformational freedom of ferrocene nucleus is modified by interannular bridging has been investigated through a study spectral properties (particularly PMR) series [m]ferrocenophane derivatives. In particular, relative importance cyclopentadienyl ring tilting, ring-ring torsion, bridge mobility estimated for systems differing length.
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