On a temperature dependence of the van der waals volume parameter in cubic equations of state
作者： Lubomír Hnědkovský , Ivan Cibulka
DOI: 10.1016/0378-3812(90)85062-F
关键词: Van der Waals surface 、 Van der Waals radius 、 van der Waals force 、 Thermodynamics 、 Van der Waals strain 、 Hamaker constant 、 Chemistry 、 Van der Waals equation 、 Redlich–Kwong equation of state 、 Theorem of corresponding states
摘要: A dependence of the van der Waals volume parameter on temperature in cubic equations state is analysed from point view a consistency description compressed liquid region. The analysis shows that there may be region PϱT space where thermal pressure coefficient and isobaric expansion are negative if decreases with increasing temperature. results illustrated volume-translation method, which special case parameter.
murdoch.edu.au
elsevier.com参考文章(4)
M.A. Trebble, P.R. Bishnoi, Accuracy and consistency comparisons of ten cubic equations of state for polar and non-polar compounds Fluid Phase Equilibria. ,vol. 29, pp. 465- 474 ,(1986) , 10.1016/0378-3812(86)85045-2
Joseph J. Martin, Cubic Equations of State-Which? Industrial & Engineering Chemistry Fundamentals. ,vol. 18, pp. 81- 97 ,(1979) , 10.1021/I160070A001
Patrick Watson, Mark Cascella, David May, Salvatore Salerno, Dimitrios Tassios, Prediction of vapor pressures and saturated molar volumes with a simple cubic equation of state: Part II: The Van der Waals - 711 EOS Fluid Phase Equilibria. ,vol. 27, pp. 35- 52 ,(1986) , 10.1016/0378-3812(86)87039-X
André Péneloux, Evelyne Rauzy, Richard Fréze, A consistent correction for Redlich-Kwong-Soave volumes Fluid Phase Equilibria. ,vol. 8, pp. 7- 23 ,(1982) , 10.1016/0378-3812(82)80002-2