Molecular Paneling by Coordination: An M15L6 Hexahedral Molecular Capsule having Clefts for Reversible Guest Inclusion
作者： Kazuhiko Umemoto , Hitoshi Tsukui , Takahiro Kusukawa , Kumar Biradha , Makoto Fujita
DOI: 10.1002/1521-3773(20010716)40:14<2620::AID-ANIE2620>3.0.CO;2-E
关键词: Capsule 、 Crystallography 、 Molecular recognition 、 Self-assembly 、 Stereochemistry 、 Chemistry 、 Ethylenediamine 、 General chemistry 、 Catalysis
摘要: Only one positional isomer is obtained from the assembly of 21 small components. A triangular molecular panel with five coordination sites assembled upon complexation [PdII (en)] (en=ethylenediamine) into a unique M15 L6 hexahedral capsule (see X-ray structure). The can encapsulate/exchange organic guests reversibly through clefts at nonbinding capsule.
sci-hub.se 参考文章(30)
Rolf W. Saalfrank, Eveline Uller, Bernhard Demleitner, Ingo Bernt, Synergistic Effect of Serendipity and Rational Design in Supramolecular Chemistry ChemInform. ,vol. 31, pp. 149- 175 ,(2000) , 10.1007/3-540-46591-X_5
Nobuhiro Takeda, Kazuhiko Umemoto, Kentaro Yamaguchi, Makoto Fujita, A nanometre-sized hexahedral coordination capsule assembled from 24 components Nature. ,vol. 398, pp. 794- 796 ,(1999) , 10.1038/19734
Leonard R. MacGillivray, Jerry L. Atwood, A chiral spherical molecular assembly held together by 60 hydrogen bonds Nature. ,vol. 389, pp. 469- 472 ,(1997) , 10.1038/38985
Thomas Heinz, Dmitry M Rudkevich, Julius Rebek Jr, None, Pairwise selection of guests in a cylindrical molecular capsule of nanometre dimensions Nature. ,vol. 394, pp. 764- 766 ,(1998) , 10.1038/29501
Rolf W. Saalfrank, Armin Stark, Karl Peters, Hans Georg von Schnering, Der erste „adamantanoide” Erdalkalimetallchelatkomplex: Synthese, Struktur und Reaktivität† Angewandte Chemie. ,vol. 100, pp. 878- 880 ,(1988) , 10.1002/ANGE.19881000623
Stefan Leininger, Bogdan Olenyuk, Peter J. Stang, Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals Chemical Reviews. ,vol. 100, pp. 853- 908 ,(2000) , 10.1021/CR9601324
Makoto Fujita, Kazuhiko Umemoto, Michito Yoshizawa, Norifumi Fujita, Takahiro Kusukawa, Kumar Biradha, Molecular paneling via coordination Chemical Communications. pp. 509- 518 ,(2001) , 10.1039/B008684N
Paul N. W. Baxter, Jean-Marie Lehn, Gerhard Baum, Dieter Fenske, The Design and Generation of Inorganic Cylindrical Cage Architectures by Metal‐Ion‐Directed Multicomponent Self‐Assembly Chemistry: A European Journal. ,vol. 5, pp. 102- 112 ,(1999) , 10.1002/(SICI)1521-3765(19990104)5:1<102::AID-CHEM102>3.0.CO;2-S
Brendan F. Abrahams, Simon J. Egan, Richard Robson, A Very Large Metallosupramolecular Capsule with Cube-like 43 Topology Assembled from Twelve Cu(II) Centers and Eight Tri-Bidentate Tri-Anionic Ligands Derived from 2,4,6-Triphenylazo-1,3,5-trihydroxybenzene Journal of the American Chemical Society. ,vol. 121, pp. 3535- 3536 ,(1999) , 10.1021/JA990016T
Paul N. W. Baxter, Jean-Marie Lehn, Boris O. Kneisel, Gerhard Baum, Dieter Fenske, The Designed Self-Assembly of Multicomponent and Multicompartmental Cylindrical Nanoarchitectures Chemistry: A European Journal. ,vol. 5, pp. 113- 120 ,(1999) , 10.1002/(SICI)1521-3765(19990104)5:1<113::AID-CHEM113>3.0.CO;2-K